International audienceSurface ozone is measured since 2004 at the coastal East Antarctic station of Dumont d'Urville (DDU) and since 2007 at the Concordia station located on the high East Antarctic plateau. Ozone levels at Concordia reach a maximum of 35 ppbv in July and a minimum of 21 ppbv in February. From November to January, sudden increases of the ozone level, up to 15-20 ppbv above average, often take place. They are attributed to local photochemical ozone production as previously seen at the South Pole. The detailed examination of the diurnal ozone record in summer at Concordia suggests a local photochemical ozone production of around 0.2 ppbv h−1 during the morning. The ozone record at DDU exhibits a maximum of 35 ppbv in July and a minimum of 18 ppbv in January. Mixing ratios at DDU are always higher than those at Neumayer (NM), another coastal Antarctic station. A noticeable difference in the ozone records at the two coastal sites lies in the larger ozone depletion events occurring from July to September at NM compared to DDU, likely due to stronger BrO episodes in relation with a larger sea ice coverage offshore that site. A second difference is the large day-to-day fluctuations which are observed from November to January at DDU but not at NM. That is attributed to a stronger impact at DDU than at NM of air masses coming from the Antarctic plateau. The consequences of such a high oxidizing property of the atmosphere over East Antarctica are discussed with regard to the dimethylsulfide (DMS) chemistry

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Abstract. The Keller-Segel partial differential equation is a two-dimensional model for chemotaxis. When the total mass of the initial density is one, it is known to exhibit blow-up in finite time as soon as the sensitivity χ of bacteria to the chemo-attractant is larger than 8π. We investigate its approximation by a system of N two-dimensional Brownian particles interacting through a singular attractive kernel in the drift term.In the very subcritical case χ < 2π, the diffusion strongly dominates this singular drift: we obtain existence for the particle system and prove that its flow of empirical measures converges, as N → ∞ and up to extraction of a subsequence, to a weak solution of the Keller-Segel equation.We also show that for any N ≥ 2 and any value of χ > 0, pairs of particles do collide with positive probability: the singularity of the drift is indeed visited. Nevertheless, when χ < 2πN , it is possible to control the drift and obtain existence of the particle system until the first time when at least three particles collide. We check that this time is a.s. infinite, so that global existence holds for the particle system, if and only if χ ≤ 8π(N − 2)/(N − 1).Finally, we remark that in the system with N = 2 particles, the difference between the two positions provides a natural two-dimensional generalization of Bessel processes, which we study in details.

[1] Initiated in 1997, the year-round study of formic and acetic acids was maintained until 2011 at the coastal Antarctic site of Dumont d'Urville. The records show that formic and acetic acids are rather abundant in summer with typical mixing ratios of 200 pptv and 700 pptv, respectively. With the aim to constrain their budget, investigations of their potential marine precursors like short-chain alkenes and acetaldehyde were initiated in 2011. Acetic acid levels in December 2010 were four times higher than those observed over summers back to 1997. These unusually high levels were accompanied by unusually high levels of ammonia, and by an enrichment of oxalate in aerosols. These observations suggest that the guano decomposition in the large penguin colonies present at the site was particularly strong under weather conditions encountered in spring 2010 (important snow storms followed by sunny days with mild temperatures). Although being dependent on environmental conditions, this process greatly impacts the local atmospheric budget of acetic acid, acetaldehyde, and acetone during the entire summer season. Present at levels as high as 500 pptv, acetaldehyde may represent the major precursor of acetic acid, alkene-ozone reactions remaining insignificant sources. Far less influenced by penguin emissions, the budget of formic acid remains not fully understood even if alkene-ozone reactions contribute significantly.