The THEMIS plasma instrument is designed to measure the ion and electron distribution functions over the energy range from a few eV up to 30 keV for electrons and 25 keV for ions. The instrument consists of a pair of "top hat" electrostatic analyzers with common 180°×6°fields-of-view that sweep out 4π steradians each 3 s spin period. Particles are detected by microchannel plate detectors and binned into six distributions whose energy, angle, and time resolution depend upon instrument mode. On-board moments are calculated, and processing includes corrections for spacecraft potential. This paper focuses on the ground and in-flight calibrations of the 10 sensors on five spacecraft. Cross-calibrations were facilitated by having all the plasma measurements available with the same resolution and format, along with spacecraft potential and magnetic field measurements in the same data set. Lessons learned from this effort should be useful for future multi-satellite missions.

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The exclusive use of carbonate reference materials is a robust method for the standardization of clumped isotope measurements • Measurements using different acid temperatures, designs of preparation lines, and mass spectrometers are statistically indistinguishable • We propose new consensus values for a set of 7 carbonate reference materials and updated guidelines to report clumped isotope measurements

Many chemical reactions in atmospheric aerosols and bulk aqueous environments are influenced by the surrounding solvation shell, but the precise molecular interactions underlying such effects have rarely been elucidated. We exploited recent advances in isomer-specific cluster vibrational spectroscopy to explore the fundamental relation between the hydrogen (H)-bonding arrangement of a set of ion-solvating water molecules and the chemical activity of this ensemble. We find that the extent to which the nitrosonium ion (NO+)and water form nitrous acid (HONO) and a hydrated proton cluster in the critical trihydrate depends sensitively on the geometrical arrangement of the water molecules in the network. Theoretical analysis of these data details the role of the water network in promoting charge delocalization.