Poly (vinyl alcohol) based composite films with different loadings of cellulose nanofibrils were prepared using a solvent casting method and their tensile, optical and wettability properties were tested. The morphology of both neat poly (vinyl alcohol) and nanocomposites was explored by using a field emission scanning electron microscope technique. Results indicated that the tensile strength and Young's modulus of poly (vinyl alcohol) composite films were significantly improved with the increase of cellulose nanofibrils loading. However, the percentage of elongation at break decreased with increasing of cellulose nanofibrils. The films became increasingly opaque with increasing cellulose nanofibrils contents, although the composites also retained moderate transparency. The samples containing cellulose nanofibrils exhibited higher hydrophobicity compared with that of neat poly (vinyl alcohol). Field emission scanning electron microscope micrographs revealed that the cellulose nanofibrils were homogeneously dispersed in the poly (vinyl alcohol) matrix.
Polypropylene/wood flour/organoclay hybrid nanocomposites were melt-compounded in an internal mixer at 190 oC and 60 rpm rotor speed. Then samples were fabricated by injection molding. Effects of immersion temperature on the water uptake of hybrid nanocomposite were investigated. To meet this objective, water absorption of samples was determined after 24 h immersion in distilled water at different temperatures (25, 50, 75, and 100 °C). Results indicated that immersion temperature had a significant influence on the water absorption of composites. By increasing the temperature, water absorption increases as well. The maximum water absorption of composite is decreased by increasing the nanoclay and compatibilizer content. The morphology of nanoclay was determined by X-ray diffraction (XRD) and transmission electron microscopy. The effect of morphology on water absorption was also evaluated. Due to inadequate compatibilizer, exfoliated morphology of nanoclay was not obtained, but there was evidence of intercalation. The order of intercalation for samples containing 3 phc was higher than that of 6 phc at the same PP-g-MA content due to some agglomerations of organoclay.
The effects of different chemical solvents on the technological properties of hemp fibrereinforced polypropylene composites were evaluated in this experimental work. Composite profiles consisting of hemp fibre and polypropylene at 50% weight ratios, with 2% of coupling agent were fabricated using melt compounding followed by injection moulding. The composite specimens were then immersed in CH 3 COOH, HNO 3 , H 2 SO 4 , NaOH, NH 3 , and C 6 H 5 NH 2 for different time intervals. Then, the weight loss and mechanical strength of samples were measured. Results indicated that the chemical reagents had significant effect on the weight loss of the composites. The weight loss ratio of the control samples was lower than that of those samples exposure to the chemical solvents. The tensile strength and modulus, and impact strength of composite specimens decreased after exposure to the chemical solvents. The highest mechanical reduction was observed in the case of NaOH. SEM micrographs showed that the extent of degradation increased in composites when they are exposed to chemical solvents.
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