Waste recycling is an essential part of waste management. The concrete industry allows the use of large quantities of waste as a substitute for a conventional raw material without sacrificing the technical properties of the product. From a circular economy point of view, this is an excellent opportunity for waste recycling. Nevertheless, in some cases, the recycling process can be undesirable because it does not involve a net saving in resource consumption or other environmental impacts when compared to the conventional production process. In this study, the environmental performance of conventional absorption porous barriers, composed of 86 wt % of natural aggregates and 14 wt % cement, was compared with barriers composed of 80 wt % seashell waste and 20 wt % cement through an attributional cradle-to-grave life cycle assessment. The results show that, for the 11 environmental impact categories considered, the substitution of the natural aggregates with seashell waste involves higher environmental impacts, between 32% and 267%. These results are justified by the high contribution to these impacts of the seashell waste pre-treatment and the higher cement consumption. Therefore, the recycling of seashells in noise barrier manufacturing is not justified from an environmental standpoint with the current conditions. In this sense, it could be concluded that life cycle assessments should be carried out simultaneously with the technical development of the recycling process to ensure a sustainable solution.
The reuse of two wastes from coal combustion in the manufacture of panels to be used as building materials or in the protection of metal structures against fire was analysed in this study. The panels were composed of 100% coal combustion by-products. The wastes used were fly ashes and flue gas desulfurisation gypsum from the combustion of coal in a Spanish power plant. The gypsum was previously calcined for 6 h at 150°C. Different mixtures of gypsum and fly ash were tested. The mixtures were kneaded with water until a homogeneous paste was achieved, with which moulds were filled. After 28 d at ambient temperature, the panels were subjected to different physical (density, pH and humidity), mechanical (compressive strength and surface hardness) and fire-resistance tests. Moreover, leaching tests were applied to the fly ash and gypsum. The results obtained were evaluated with the requirements established in some European standards for commercial gypsum products. The fire resistance of the panels under study was found to be higher than that of commercial gypsum and they also showed good mechanical properties.
Although fly ash is commonly used as an additive to cement, large amounts of this material are disposed in landfills. To mitigate, it would be interesting to develop new products in which fly ash can be easily used and required in large quantities. In this work, fly ash is added to manufacture eco-friendly materials with acceptable acoustic and non-acoustic properties and a low cost. We built a barrier composed of fly ash (60 wt.%), type II Portland cement (25 wt.%), vermiculite (14.5 wt.%) and polypropylene fibers (0.5 wt.%). The barrier complied with the mechanical requirements of European standards. The sound absorption coefficient and the airborne sound insulation were determined in a reverberation room, and the barrier was classified as A2 and B3. No leaching problems were observed.
The construction industry’s high demand for natural resources, combined with the waste generated by agriculture, creates an opportunity for the circular economy. This experiment used the CaCO3 found in scallop shells as an ingredient for the manufacture of fire-resistant materials, replacing gypsum in compositions of 40% and 50% by weight. The mechanical compressive strength was estimated for both freeze-thaw cycles and acid and sulfate attacks. The cost of disposing of scallop shell waste in landfills, savings from substitution, and the payback period relative to the amount of production were determined. The compressive strength of the materials decreased by 80% when subjected to freeze-thaw cycles and sulfate attack. In response to acid attack, they showed a 100% increase in strength during the first three weeks and a decrease thereafter. The savings amounted to $46.36 (22.4%) for 40% replacement and $58.93 (28.4%) for 50%. Respectively, return on investment is achieved at 800- and 630-per-metric ton produced. The difference between the costs of waste disposal (in aquaculture) and the potential savings from using CaCO3 as a raw material (in construction) creates an opportunity for commercialization between the two industries, serves as a reference for decision-makers, and complies with circular economy principles, reducing both inputs of raw materials and outputs of waste.
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