A facile two-step method was developed
to prepare core/shell ZnO/rGO
particles from ZIF-8/rGO composites. ZIF-8 particles were first grown
at the surface of rGO sheets. Next, ZIF-8 particles were transformed
into ZnO particles by thermal decomposition under air at 500 °C.
All materials were characterized by scanning electron microscopy,
transmission electron microscopy, X-ray diffraction, Raman spectroscopy,
thermogravimetric analysis, and Brunauer–Emmett–Teller
analyses. Results obtained show that ZIF-8 particles strongly associate
with rGO sheets and that the calcination of this material produces
porous core/shell ZnO/rGO particles with an average diameter of ca.
40 nm. The wt % of rGO associated with ZIF-8 particles was varied
from 5 to 20%. The ZnO/rGO (10%) particles exhibit the highest photocatalytic
activity for the degradation of the Orange II dye under simulated
solar light irradiation of weak intensity (5 mW/cm
2
). This
high photocatalytic activity was demonstrated to originate from superoxide
O
2
•–
radicals due to the efficient
trapping of photogenerated electrons in ZnO by rGO.
Photocatalysts composed of graphitic carbon nitride (g-CN) and TiO2 were efficiently prepared by thermolysis of the MIL-125(Ti) metal organic framework deposited on g-CN. The heterojunction between the 12 nm-sized TiO2 nanoparticles and g-CN was well established and the highest photocatalytic activity was observed for the g-CN/TiO2 (3:1) material. The g-CN/TiO2 (3:1) composite exhibits high visible light performances both for the degradation of pollutants like the Orange II dye or tetracycline but also for the production of hydrogen (hydrogen evolution rate (HER) up to 1330 μmolh−1g−1 and apparent quantum yield of 0.22% using NiS as a cocatalyst). The improved visible light performances originate from the high specific surface area of the photocatalyst (86 m2g−1) and from the efficient charge carriers separation as demonstrated by photoluminescence, photocurrent measurements, and electrochemical impedance spectroscopy. The synthetic process developed in this work is based on the thermal decomposition of metal organic framework deposited on a graphitic material and holds huge promise for the preparation of porous heterostructured photocatalysts.
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