The feasibility of separating the azeotropic mixture of ethanol-water using microbubble-mediated batch distillation is presented. The effects of the depth of the liquid mixture in the bubble tank and of the inlet air microbubble temperature on the process efficiency were investigated. The enrichment of ethanol in the vapor phase was higher than that achieved at equilibrium conditions for all liquid ethanol mole fractions considered, including the azeotrope. On decreasing the depth of the liquid mixture and increasing the temperature of the air microbubbles, the separation efficiency of ethanol was improved. Ethanol with purity of about 98.2 vol % was obtained using the lowest liquid level (3 mm) in conjunction with the highest air microbubble temperature (908C). Separation was achieved with a small rise in the temperature of the liquid mixture (48C) at a depth of 3 mm and evaporation time of 90 min making this system suitable for treating thermally sensitive mixtures.
A computational model of a single
gas microbubble immersed in a
liquid of ethanol–water mixture is developed and solved numerically.
This complements earlier binary distillation experiments in which
the ethanol–water mixture is stripped by hot air microbubbles
achieving around 98% vol. ethanol from the azeotropic mixture. The
proposed model has been developed using Galerkin finite element methods
to predict the temperature and vapor content of the gas microbubble
as a function of its residence time in the liquid phase. This model
incorporates a novel rate law that evolves on a time scale related
to the internal mixing of microbubbles of 10–3s.
The model predictions of a single bubble were shown to be in very
good agreement with the existing experimental data, demonstrating
that the ratio of ethanol to water in the microbubble regime are higher
than the expected ratios that would be consistent with equilibrium
theory for all initial bubble temperatures and all liquid ethanol
mole fractions considered and within the very short contact times
appropriate for thin liquid layers. Our previous experiments showed
a decrease in the liquid temperature with decreasing liquid depth
in the bubble tank, an increase in the outlet gas temperature with
decreasing liquid depth, and an improvement in the stripping efficiency
of ethanol upon decreasing the depth of the liquid mixture and increasing
the temperature of the air microbubbles, all of which are consistent
with the predictions of the computational model.
In this work, microbubble dispersed air flotation technique was applied for cadmium ions removal from wastewater aqueous solution. Experiments parameters such as pH (3, 4, 5, and 6), initial Cd(II) ions concentration (40, 80, and 120 mg/l) contact time( 2, 5, 10 , 15, and 20min), and surfactant (10, 20and 40mg/l) were studied in order to optimize the best conditions .The experimental results indicate that microbubbles were quite effective in removing cadmium ions and the anionic surfactant SDS was found to be more efficient than cationic CTAB in flotation process. 92.3% maximum removal efficiency achieved through 15min at pH 5, SDS surfactant concentration 20mg/l, flow rate250 cm3/min and at 40mg/l Cd(II) ions initial concentration. The removal efficiency of cadmium ion was predicted through 11 neurons hidden layer, with a correlation coefficient of 0.9997 between ANN outputs and the experimental data and through sensitivity analysis, pH was found to be most significant parameter (25.13 %).The kinetic flotation order for cadmium ions almost first order and the removal rate constant (k) increases with decreasing the initial metal concentration.
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