The area chosen for the present study is Dhule district, which belongs to the drought prone area of Maharashtra State, India. Dhule district suffers from water problem, and therefore, there is no extra water available to supply for the agricultural and industrial growth. To understand the lithological characters in terms of its hydrogeological conditions, it is necessary to understand the geology of the area. It is now established fact that the geophysical method gives a better information of subsurface geology. Geophysical electrical surveys with four electrodes configuration, i.e., Wenner and Schlumberger method, were carried out at the same selected sites to observe the similarity and compared both the applications in terms of its use and handling in the field. A total 54 VES soundings were carried out spread over the Dhule district and representing different lithological units. The VES curves are drawn using inverse slope method for Wenner configuration, IPI2 win Software, and curve matching techniques were used for Schlumberger configuration. Regionwise lithologs are prepared based on the obtained resistivity and thickness for Wenner method. Regionwise curves were prepared based on resistivity layers for Schlumberger method. Comparing the two methods, it is observed that Wenner and Schlumberger methods have merits or demerits. Considering merits and demerits from the field point of view, it is suggested that Wenner inverse slope method is more handy for calculation and interpretation, but requires lateral length which is a constrain. Similarly, Schlumberger method is easy in application but unwieldy for their interpretation. The work amply proves the applicability of geophysical techniques in the water resource evaluation procedure. This technique is found to be suitable for the areas with similar geological setup elsewhere.