ABSTRACT:Gasohol is a mixture of premium petrol (gasoline) with alcohol, in this case ethanol. The use of gasohol can reduce fuel consumption without having to modify the existing engine. Therefore, this research is conducted to study the characteristics and performance of gasohol in various mixing ratios, which includes analysis of physical properties and the use of gasohol in the machine. Results show that the addition of technical ethanol at 7.0169%v increases the value of gasohol vapor pressure on the value of 8.6682 psi (7.7 psi for regular gasoline). Gasohol with technical ethanol content above 30%v decreases vapor pressure, promotes phase separation, and causes a sharp drop in temperature from 40%v distillation. In term of corrosivity, gasohol with up to 50%v ethanol content has the same corrosion level with regular gasoline, which is corrosion level 1A. Based on gasohol characteristics test, it is known that gasohol with technical ethanol content below 20%v can be used as a fuel substitute for gasoline. Real-time performance test of gasohol in engines has shown that the addition of ethanol content in gasohol tend to increase the engine power at a certain compression ratio, but it also increases fuel consumption because the heat value of ethanol is lower than gasoline. Machine in gasohol with ethanol content below 20%v can operate smoothly without having to modify the engine. Based on the studies that have been done, gasohol in the range of 10%v ethanol content is well-functioned as a substitute for gasoline fuel and meets fuel specifications required by the General Director of Oil and Gas. The feasibility of using gasohol as an alternative fuel can be studied further.
The studies on the hydrocracking process to obtain the fuel by cracking of the carbon chain from the hydrocarbon compound both in the form of gas and liquid fuels have been carried-out massively by researchers over three decade. In the present experimental study, heavy hydrocarbon represented by asphaltic base materials (named as Extracted Asbuton) and paraffinic (waxy residue from Cepu oil refinery) were used as the object of the study; by observing the differences of the reaction mechanisms and the results that can be obtained. Here the operational conditions such as pressure, temperature, and time as well as the kinds of catalyst were considered as the main parameters. The experiments were carried-out under the similar operating condition such as temperature around 350 – 500oC, pressure around 5 up to 15 atmospheres, and evaporation time was (1 – 3) hours. As a result, it was obtained (a) the higher the temperature, pressure, and heating time, the higher hydrocracking conversion both of hydrocarbons, (b) reaction mechanism of hydrocracking by using asphalt extract as the material follows the Model 3 of the present work, in which asphalt vapor was trapped in catalyst surface, meanwhile the waxy residue followed the Model 1, (c) under the same condition, the conversion of asphalt extract was smaller than waxy residue, and (d) the conversion of asphalt extract using Pt/Pd catalyst was higher than γ-Alumina catalyst.Keywords : Asbuton, Waxy Residue, Hydrocracking, Reaction Mechanisms.
The goal of this research is to investigate the effect of surfactant and polymer found in the market and developed in the laboratory such as Sodium Ligno Sulfonat, Poly Vynil Alcohol (PVA) and Partially Hydrolyzed Polyacrylamide (HPAM) polymer on the oil recovery which can be used to optimize recovery and minimize residual oil in the reservoir by: lowering the oil / water interfacial tension and improving mobility ratio. The effectiveness of chemicals was tested through micro displacement using artificial reservoir as porous medium. The procedure of operation is as follows: initially the reservoir model was filled with brine until it was 100 % saturated. Then to represent oil migration, oil was injected into the medium until minimum water saturation (Swc) of about 30 % is reached. After this, the medium was flooded by the same brine until minimum oil saturation, Sor, was reached, which was about 10 %. The oil remaining in the reservoir model after this water flood was then subjected to the injection of various chemicals for additional oil recovery. A set of mathematical model of oil displacement from porous media using water and polymer flooding has also been developed, based on fundamental theories of two phase flow. Since the model includes the material balance of the water, surfactant and polymer, the concentration of the surfactant and polymer at any position and time can be predicted. The oil displacement experiments show that as much as 20 % to 60 % of remaining oil can be recovered by flooding it with the chemical developed in the laboratory. The results also show the oil recovery depends on chemical, chemical concentration, pressure and temperature in the model reservoir, and crude oil. It turns that the mathematical models proposed were in a good agreement with the experimental data.
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