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[1] We present results from the first zonal transect of iron, aluminum, and manganese conducted from the western source region of the Equatorial Undercurrent (EUC) to the central equatorial Pacific. Trace metals were elevated along the slope of Papua New Guinea and within the New Guinea Coastal Undercurrent (NGCU), which is the primary Southern Hemisphere entry path of water to the EUC. Subsurface maxima in total acid-soluble iron, aluminum, and manganese were evident in the EUC. These maxima were generally greatest in the western equatorial Pacific and decreased in magnitude eastward. Maxima in iron and aluminum persisted to 140°W; maxima in manganese extended to 175°W. Iron and manganese maxima were deeper (25-75 m) than aluminum maxima and located in the lower EUC, which undergoes less interior ocean mixing than shallower waters. The depth of the aluminum subsurface maxima correlated strongly (r = 0.88) with the depth of the EUC velocity maximum. Surface waters were enriched in aluminum and manganese offshore of Papua New Guinea. Surface metal concentrations decreased eastward throughout the western warm pool up to the longitude (∼180°W) of the salinity front. Detrital sediment input from either direct riverine input or sediment resuspension appeared to be the primary mechanism of supplying metals to the NGCU. We estimated eastward fluxes of metals in the EUC and found greatest fluxes in the western equatorial Pacific between 160°E and 165°E, except for aluminum. Fluxes of aluminum and, to a lesser extent, manganese increased concurrently with water volume transport in the central equatorial Pacific. Iron transport in the EUC remained constant east of the dateline, apparently due to the combined effects of dilution by meridional entrainment and scavenging. Iron was mobilized in a highly active western boundary current region and transported eastward in the lower EUC.

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Total acid-soluble and dissolved Cd, Co, Cr, Cu, Ni, Pb, and Zn concentrations in the water column of a seasonally anoxic lake (Lake Sammamish, Washington) were measured on a monthly basis during the course of a year. These data, in conjunction with Fe, Mn, sulfide, and nutrient data, are used to assess the biochemical processes controlling the distribution of trace metals in the lake and how the importance of these processes varies with time. Thermodynamic calculations are used to examine changes in dissolved metal speciation in the bottom waters during the year and to assess the saturation state of metal-sulfide phases. Spatial and temporal changes in the redox conditions of the bottom waters result in increases in dissolved Co and Ni concentrations, peaks in particulate Co profiles, decreases in dissolved Cu and Cr concentrations, and significant changes in dissolved metal speciation during stagnation. The rcdox-driven cycling of Fe and Mn in the hypolimnion has a dramatic effect on Co distributions, a slight effect on Ni concentrations, and virtually no effect on Cd, Cu, Cr, and Zn concentrations. Biological uptake and regeneration processes result in a correlation between Zn and silicate concentrations throughout the water column, and it appears that biological cycling may also influence the distribution of Cd. During the sulfidic phase of stagnation dissolved Cd concentrations in the bottom waters may be controlled by metal-sulfide precipitation, Cr(V1) is probably reduced to more particle-reactive Cr(II1) and removed by settling particles, and Cu(H) is most likely reduced to Cu(1) and precipitated as a metal-sulfide phase.Gradual changes in the redox state of hypolimnetic waters in seasonally anoxic lakes provide an excellent opportunity to study the response of elements to changing biochemical conditions.Past studies have shown that redox-sensitive elements, such as N, Mn, Fe, and S, show large temporal and spatial variations in their concentrations and distributions in seasonally anoxic