Low efficiencies and costly electrode materials have limited harvesting of thermal energy as electrical energy using thermo-electrochemical cells (or "thermocells"). We demonstrate thermocells, in practical configurations (from coin cells to cells that can be wrapped around exhaust pipes), that harvest low-grade thermal energy using relatively inexpensive carbon multiwalled nanotube (MWNT) electrodes. These electrodes provide high electrochemically accessible surface areas and fast redox-mediated electron transfer, which significantly enhances thermocell current generation capacity and overall efficiency. Thermocell efficiency is further improved by directly synthesizing MWNTs as vertical forests that reduce electrical and thermal resistance at electrode/substrate junctions. The efficiency of thermocells with MWNT electrodes is shown to be as high as 1.4% of Carnot efficiency, which is 3-fold higher than for previously demonstrated thermocells. With the cost of MWNTs decreasing, MWNT-based thermocells may become commercially viable for harvesting low-grade thermal energy.
Polymers are usually considered thermal insulators, because the amorphous arrangement of the molecular chains reduces the mean free path of heat-conducting phonons. The most common method to increase thermal conductivity is to draw polymeric fibres, which increases chain alignment and crystallinity, but creates a material that currently has limited thermal applications. Here we show that pure polythiophene nanofibres can have a thermal conductivity up to ∼ 4.4 W m(-1) K(-1) (more than 20 times higher than the bulk polymer value) while remaining amorphous. This enhancement results from significant molecular chain orientation along the fibre axis that is obtained during electropolymerization using nanoscale templates. Thermal conductivity data suggest that, unlike in drawn crystalline fibres, in our fibres the dominant phonon-scattering process at room temperature is still related to structural disorder. Using vertically aligned arrays of nanofibres, we demonstrate effective heat transfer at critical contacts in electronic devices operating under high-power conditions at 200 °C over numerous cycles.
Advances in the synthesis and scalable manufacturing of single-walled carbon nanotubes (SWCNTs) remain critical to realizing many important commercial applications. Here we review recent breakthroughs in the synthesis of SWCNTs and highlight key ongoing research areas and challenges. A few key applications that capitalize on the properties of SWCNTs are also reviewed with respect to the recent synthesis breakthroughs and ways in which synthesis science can enable advances in these applications. While the primary focus of this review is on the science framework of SWCNT growth, we draw connections to mechanisms underlying the synthesis of other 1D and 2D materials such as boron nitride nanotubes and graphene.
Thermal conductivity of nanocrystalline silicon by direct molecular dynamics simulation J. Appl. Phys. 112, 064305 (2012) Electrical and heat conduction mechanisms of GeTe alloy for phase change memory application J. Appl. Phys. 112, 053712 (2012) Thermal rectification and phonon scattering in silicon nanofilm with cone cavity J. Appl. Phys. 112, 054312 (2012) Analysis of the "3-Omega" method for substrates and thick films of anisotropic thermal conductivity This work describes an experimental study of thermal conductance across multiwalled carbon nanotube ͑CNT͒ array interfaces, one sided ͑Si-CNT-Ag͒ and two sided ͑Si-CNT-CNT-Cu͒, using a photoacoustic technique ͑PA͒. Well-anchored, dense, and vertically oriented multiwalled CNT arrays have been directly synthesized on Si wafers and pure Cu sheets using plasma-enhanced chemical vapor deposition. With the PA technique, the small interface resistances of the highly conductive CNT interfaces can be measured with accuracy and precision. In addition, the PA technique can resolve the one-sided CNT interface component resistances ͑Si-CNT and CNT-Ag͒ and the two-sided CNT interface component resistances ͑Si-CNT, CNT-CNT, and CNT-Cu͒ and can estimate the thermal diffusivity of the CNT layers. The thermal contact resistances of the one-and two-sided CNT interfaces measured using the PA technique are 15.8± 0.9 and 4.0± 0.4 mm 2 K/W, respectively, at moderate pressure. These results compare favorably with those obtained using a steady state, one-dimensional reference bar method; however, the uncertainty range is much narrower. The one-sided CNT thermal interface resistance is dominated by the resistance between the free CNT array tips and their opposing substrate ͑CNT-Ag͒, which is measured to be 14.0± 0.9 mm 2 K / W. The two-sided CNT thermal interface resistance is dominated by the resistance between the free tips of the mating CNT arrays ͑CNT-CNT͒, which is estimated to be 2.1± 0.4 mm 2 K/W.
Continuously operating thermo-electrochemical cells (thermocells) are of interest for harvesting low-grade waste thermal energy because of their potentially low cost compared with conventional thermoelectrics. Pt-free thermocells devised here provide an output power of 12 W m for an interelectrode temperature difference (ΔT) of 81 °C, which is sixfold higher power than previously reported for planar thermocells operating at ambient pressure.
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