Hydrophobically modified ethoxylated urethanes (HEURs) are associative polymers that, compare to others, are far less sensitive to solution parameters, especially pH and ionic strength. Therefore, they are widely used as rheology modifiers in many different waterborne systems such as inks, coatings, emulsions, etc. In solutions, HEURs form transient networks through molecular associations between their hydrophobic groups. The transient network formation and its characteristics are responsible for the rheological properties and depend on the HEUR chains architecture. Many parameters such as molecular weight, size and nature of hydrophobic groups, polymer concentration, etc must be controlled to tune the several physicochemical properties of HEUR solutions. This article aims to give an overview of the HEUR studies reported in the literature in order to highlight the structure/rheological properties relationship. The article also draws attention to new trends in HEURs with innovative architectures and stimuli-responsive properties.

The aminolysis of five-membered cyclic carbonates which results in polyhydroxyurethanes (PHUs) is one of the most promising synthetic pathway to achieve isocyanate-free polyurethanes (NIPUs), one of the main industrial challenges...