Aim(a) To determine the spatial distributions and levels of major and minor elements, as well as heavy metals, in water, sediment, and biota (plant and fish) in Al-Hammar Marsh, southern Iraq, and ultimately to supply more comprehensive information for policy-makers to manage the contaminants input into the marsh so that their concentrations do not reach toxic levels. (b) to characterize the seasonal changes in the marsh surface water quality. (c) to address the potential environmental risk of these elements by comparison with the historical levels and global quality guidelines (i.e., World Health Organization (WHO) standard limits). (d) to define the sources of these elements (i.e., natural and/or anthropogenic) using combined multivariate statistical techniques such as Principal Component Analysis (PCA) and Agglomerative Hierarchical Cluster Analysis (AHCA) along with pollution analysis (i.e., enrichment factor analysis)MethodsWater, sediment, plant, and fish samples were collected from the marsh, and analyzed for major and minor ions, as well as heavy metals, and then compared to historical levels and global quality guidelines (WHO guidelines). Then, multivariate statistical techniques, such as PCA and AHCA, were used to determine the element sourcing.ResultsWater analyses revealed unacceptable values for almost all physio-chemical and biological properties, according to WHO standard limits for drinking water. Almost all major ions and heavy metal concentrations in water showed a distinct decreasing trend at the marsh outlet station compared to other stations. In general, major and minor ions, as well as heavy metals exhibit higher concentrations in winter than in summer. Sediment analyses using multivariate statistical techniques revealed that Mg, Fe, S, P, V, Zn, As, Se, Mo, Co, Ni, Cu, Sr, Br, Cd, Ca, N, Mn, Cr, and Pb were derived from anthropogenic sources, while Al, Si, Ti, K, and Zr were primarily derived from natural sources. Enrichment factor analysis gave results compatible with multivariate statistical techniques findings. Analysis of heavy metals in plant samples revealed that there is no pollution in plants in Al-Hammar Marsh. However, the concentrations of heavy metals in fish samples showed that all samples were contaminated by Pb, Mn, and Ni, while some samples were contaminated by Pb, Mn, and Ni.Discussion and conclusionsDecreasing of Tigris and Euphrates discharges during the past decades due to drought conditions and upstream damming, as well as the increasing stress of wastewater effluents from anthropogenic activities, led to degradation of the downstream Al-Hammar Marsh water quality in terms of physical, chemical, and biological properties. As such properties were found to consistently exceed the historical and global quality objectives. However, element concentration decreasing trend at the marsh outlet station compared to other stations indicate that the marsh plays an important role as a natural filtration and bioremediation system. Higher element concentrations in winter were due to ...
Heavy metals concentration in the soils and sediments has increased worldwide during the last century as a result of the rapid increase in population which combined by an increase in human activity as agriculture, industrial and many other activities. Ten soil and three river sediment samples were collected from 10 main sampling stations at Shatt Al-Hilla River from Sada area to Dora Bridge in Babylon province. The chemical analysis of the sedimentation sample in the laboratory included pH calculation, electrical conductivity (EC) (Cation Exchange Capacity (CEC), organic matter (OM), and heavy metals as (Mn, Ni, Cr, Zn, Cu, Co, Pb, Cd, As and Fe). Indirect geochemical background (IGB) of heavy metal was calculated by the iterative 2 standard deviations (SD) method. The results of enrichment factor for heavy metals of the soil and sediment show that the all heavy metals in the studied samples were within Ef<2 indicate to depletion to minimal enrichment (i.e. no or minimal pollution). While Cd in the sample (5), Co in the sample (7), Cr in the sample (8) and Mn in the sample (1S) are within 2 ≤ EF < 5 indicate to Moderate enrichment. Contamination factor (Cf) for heavy metals of soil and sediment show that the all heavy metals in the studied samples were within Cf < 1 -Low contamination. While Sample "2" (Cd, Fe), sample "3" (Ni, Cr, Pb, and Cd), sample "4" (Mn, Fe) and sample "8" (Cr) are within 1 ≤ Cf < 3 moderate contamination. Pollution load index result of all the soil and sediment samples are less than one indicate that "no pollution" are present, except sample 3 where the PLI value higher than 1 indicates the samples have been "polluted ". The modified degree of contamination (mCd) data indicate nil to a low degree of contamination for all of the soil and sediments samples.
This study focused on the soil of the Al-Khassa Sub Basin, thirty-four soil samples were collected from different areas of land use and differences in human activity. Physicochemical properties of the soil were examined Hydrogen Potential (pH), Organic Matter (O.M), Loss Of Ignition (L.O.I), Total Organic Carbon (TOC), Cation Exchange Capacity (CEC) and Total Hydrocarbon (THC). Hydrogen Potential (pH) showed that the soil is alkaline above seven with a mean 7.98. Organic Matter (O.M) of the study area with a mean 1.28 % and high value found in Agricultural areas.Cation Exchange Capacity (CEC) with a mean 42.64 (cmol/kg) that is proportional to the granular size of the soil that silty clay. Both Total Organic Carbon (TOC) and Total Hydrocarbon (THC) acceptable concentration values compared to the soils of the arid region. In the present study abundant elements (Calcium (Ca), Silicon (Si), Aluminum (Al), Magnesium (Mg), Sulfur (S), Potassium (K), Chloride (Cl), Titanium (Ti) and Phosphorous (P) ) and Trace element(Chromium (Cr), Manganese (Mn), Nickel (Ni), Zinc (Zn), Vanadium(V), Copper(Cu), Lead(Pb), Arsenic (As), Cobalt (Co), Mercury (Hg) and Molybdenum (Mo)) that have been analyzed in this study and compared with the limits to elements distribution in world soil and local study of Lesser Zab. Elements that are higher than standard Ca, Cl, Cu, As,Hg, Mo, Zn because of excessive use of fertilizers and pesticides and poor irrigation practice and other anthropogenic sources. High concentration elements (Ni, Ca, Co) as a result of the weathering of the parent rocks, it occurs naturally in soils. Other elements that were partially higher than the standard is (K, Cr, P, S, Mg( only in dense agricultural areas. Elements that were lower than Standard (Ti, Al, Si, Mn, V, Pb) represent the unpolluted elements at some locations the sub-basin because they are elements that increase in urban and industrial areas that are not available in the Al-Khassa Sub Basin, main activity and land use of sub basin were rural area and cultivated land. The results of the enrichment factor (EF) and the contamination factor (CF) are calculated for contamination assessment. The Enrichment factor (EF) of the sub-basin is EF 2 depletion to minimal enrichment, indicating no or minimal pollution, but there is a real beginning of contamination of the magnesium element EF 2-5 moderate enrichment, indicating a real beginning of contamination of the magnesium element. indicating of moderate pollution due to the presence of farms that were use of magnesium sulfate fertilizers by villagers at sedan. The results of the Contamination Factor (CF) showed that the region is low to moderate contamination Except for the contamination factor of magnesium in Mam Rash (S22), Belgrad (S10) was very high degree of contamination of Cf > 6, and in Sedan (S25), Gurgay Shammar (S11), and Obarick (S32) was considerable degree of contamination of magnesium 3 < Cf < 6 because of the three villages was agricultural area that use of magnesium fertilizer. Phosphor (P) contamination factor is moderate in Heon (S7), Ali Makaeel (S20) because they are villages that use phosphate fertilizers beside occurrence of poultry farms.
The current study focuses on the assessment of pollution indicators and health risks of heavy elements in the surface soil of Samarra City. Twelve soil sample collected from different sites in Samarra City, analysis of soil sample to find the heavy metals concentrations which As,
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