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Green polymers as corrosion inhibitors are gradually used to protect metal in solution environment. A polyaspartic acid threonine derivative (PASP-Thr) was synthesized and its structure was characterized by Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance. The corrosion inhibition effect of polyaspartic acid (PASP) and PASP-Thr on carbon steel in simulated cooling water was investigated by weight loss tests and electrochemical measurements. Experimental results show PASP-Thr as a mixedtype inhibitor exhibits higher corrosion inhibition efficiency than PASP, and the inhibition efficiency of PASP-Thr reached 93.06% at the dosage was 200 mg L −1 . The carbon steel surface in different situations was analyzed using atomic force microscope, scanning electronic microscope/energy dispersive X-ray, and FTIR, demonstrates the formation of a protective film on carbon steel surface. The inhibition effect of PASP-Thr was primarily attributed to the protective film formed on steel surface by physical and chemical adsorption. Moreover, quantum chemical calculation elaborated the relationship between the inhibition efficiency and the PASP-Thr molecular structure.

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The flow characteristics of the blade unit of a tridimensional rotational flow sieve tray were investigated. First, the flow patterns are defined under different liquid arrangement methods. They are bilateral film flow, continuous perforated flow, and dispersion‐mixing flow in overflow distribution, film and jet flow and jet and mixed flow in spray distribution. Second, the time and frequency domain analysis of the differential pressure pulsation signal in the blade unit is carried out, the main frequencies range is 2.0−5.5 Hz. The influence of perforation and mixing intensity on the flow pattern transition is clarified. Third, the rotational flow ratio of the gas–liquid phase is measured, the gas phase rotational flow range is 0.55–0.78, and the liquid phase range is 0.15–0.42. The influence of the operating conditions on the distribution of the rotational and perforated flow is investigated. Finally, a prediction model for the rotational flow ratio is proposed.

This study reports the modification of commercial cation-exchange membrane by layer-by-layer adsorption of polyethyleneimine and poly(acrylic acid) (PAA) to endow them with monovalent ion selectivity. The chemical and morphological changes of the modified membrane surface were examined by ATR-FTIR and SEM, respectively. The permselectivity for monovalent cations of the membranes was investigated by electrodialysis experiments. The effects of deposited bilayer number, the salt concentration, and pH of the dipping polyelectrolyte solutions on selectivity were investigated. Meanwhile, the resistance of membranes was measured taking energy consumption into consideration. The polyelectrolyte multilayer was crosslinked using epichlorohydrin to improve stability, and the durability of the composite membrane was studied. Separation mechanism of the composite membrane was also investigated. It is demonstrated that the bivalent cations are mainly rejected by electrostatic repulsion from the positive charge on the surface of the composite membranes. The sieving effect of the dense structure of skin layer becomes more pronounced with the number of deposited layers increased.

Graphene oxide (GO) is expected to be used in the field of waterborne polyurethane (WPU) anti-corrosive coatings due to its excellent barrier property, but the poor dispersibility of GO limits its application. The hydrophilic modification of GO, although improving its dispersity, will greatly reduce its anti-corrosive property. Here, a new method is provided to avoid seeking an appropriate modifier blindly. Via the interaction between the epoxy group and amine group, the aminated GO (NGO) can be modified by (3-glycidyloxypropyl) trimethoxysilane (KH560) functionalized-silica (f-SiO2) nanoparticles, while the f-SiO2 is affected by KH560 due to its relatively hydrophobic alkyl side chain. Consequently, the hydrophobicity of the f-SiO2 modified NGO (f-SGO) can be regulated just by adjusting the amount of KH560, thereby achieving the balance of excellent dispersibility and anti-corrosive performance of the f-SGO nanosheets in the WPU. The electrochemical impedance and potentiodynamic polarization results showed that the anti-corrosive performance of the WPU hybrid was greatly improved by adding the appropriate amount of f-SGO. This research provides a new idea for GO application in waterborne coatings.

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