Polyoxometalate-based MOFs afford
a great opportunity in terms
of water oxidation. Herein, a new PMOF (SYNU-1) has been
constructed with active CoMoO4 layers and TPPE ligands.
In SYNU-1, each TPPE ligand bridges eight Co(II) and
Mo(VI) cations to give a 3D (3,4,5)-connected (62·83·10)(63)(65·85)
framework. SYNU-1 CPE exhibits electroreduction toward
nitrite and bromate. Furthermore, SYNU-1 catalyst demonstrates
electrocatalytic OER activity with a low overpotential of 364 mV.
Strikingly, the heterogeneous catalyst SYNU-1 shows a
high O2 yield (79.05%) for visible light water oxidation
with good stability and reusability.
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