Addressed herein, a robust methodology to generate monodisperse Pt/Rh@GO nanocomposites and their adsorption performances have been reported to clean methylene blue (MB) from the aqueous mixtures. The monodisperse Pt/Rh@GO nanocomposites were produced by the ultrasonic double solvent reduction method. Their characterization was performed by X‐ray photoelectron spectroscopy (XPS), X‐ray diffraction (XRD), high‐resolution transmission electron microscopy (HR‐TEM) and transmission electron microscopy (TEM). The mechanism of MB adsorption was explored in aqueous solutions. The adsorbtion findings revealed that the Pt/Rh@GO nanocomposites are highly effective adsorbents for MB removal offering 346.79 mg/g as the one of the record adsorption capacity. 40 minutes was observed as the equilibrium time for MB adsorption. More than that, they are reusable as they promise cleaning MB from MB‐contaminated waters maintaining 97.83 % of their initial efficacy after six sequential cycles of adsorption‐desorption.

In this study, amount of morphine from poppy capsules (Papaver somniferum) was investigated using ultrasonic assisted extraction (UAE). Response surface methodology was used to estimate effective experimental conditions on the content extraction of poppy capsules. For this purpose, solvent/solid ratio (10–20 mL/500 mg sample), pH (1–13), time (30–60 min), and temperature (30–50°C) were chosen as experimental variables. The affected response is extraction recovery values for morphine from poppy straw. For interpreting the relationship between experimental factors and response, a design table was established with combinations of three different concentrations levels of this compound in 29 trials. The second order quadratic model gave a satisfactory description of the experimental data. In our study, R-Squared (0.96), Adj-R-Squared (0.92), and Pred R-Squared (0.78) values for extraction yield display good accuracy of the derived model. The predicted optimal conditions for the highest morphine level (3.38 mg morphine/500 mg-sample) were found at 19.99 mL solvent/500 mg solid ratio, 59.94 min extraction time, 1.10 pH, and 42.36°C temperature. In the optimal extraction conditions, the experimental values are very close to the predicted values. Consequently, the response surface modeling can be achieved sufficiently to predict extraction yield from poppy straw by ultrasound assisted extraction.

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Adresses herein, monodisperse Pt nanoadsorbents have been reproducibly prepared by microwave assisted method and consist of activated carbon and platinum called as Mw-Pt NPs@AC nanocomposites. Mw-Pt NPs@AC nanocomposites were found to be extraordinary adsorption capacity for methylene blue (MB) removal from aqueous solutions. Their characterization was performed by the help of X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). The results revealed that the Mw-Pt NPs@AC nanocomposites are highly efficient adsorbents for MB removal from aqueous solutions and provide remarkable adsorption capacity (195.69 mg/g). The MB adsorption equilibrium was attained in ~75 min. In addition, reusability tests represented that Mw-Pt NPs@AC nanocomposites are quite promising for MB removal keeping 91.9% of its initial efficiency after 5 cycles of adsorption–desorption.