We present molecular line imaging observations of three massive molecular outflow sources, G333.6-0.2, G333.1-0.4, and G332.8-0.5, all of which also show evidence for infall, within the G333 giant molecular cloud (GMC). All three are within a beam size (36 arcseconds) of IRAS sources, 1.2-mm dust clumps, various masing species and radio continuum-detected Hii regions and hence are associated with high-mass star formation. We present the molecular line data and derive the physical properties of the outflows including the mass, kinematics, and energetics and discuss the inferred characteristics of their driving sources. Outflow masses are of 10 to 40 M ⊙ in each lobe, with core masses of order 10 3 M ⊙ . outflow size scales are a few tenth of a parsec, timescales are of several ×10 4 years, mass loss rates a few ×10 −4 M ⊙ /yr. We also find the cores are turbulent and highly supersonic.

Molecules with hyperfine splitting of their rotational line spectra are useful probes of optical depth, via the relative line strengths of their hyperfine components.The hyperfine splitting is particularly advantageous in interpreting the physical conditions of the emitting gas because with a second rotational transition, both gas density and temperature can be derived. For HCN however, the relative strengths of the hyperfine lines are anomalous. They appear in ratios which can vary significantly from source to source, and are inconsistent with local thermodynamic equilibrium. This is the HCN hyperfine anomaly, and it prevents the use of simple LTE models of HCN emission to derive reliable optical depths. In this paper we demonstrate how to model HCN hyperfine line emission, and derive accurate line ratios, spectral line shapes and optical depths. We show that by carrying out radiative transfer calculations over each hyperfine level individually, as opposed to summing them over each rotational level, the anomalous hyperfine emission emerges naturally. To do this requires not only accurate radiative rates between hyperfine states, but also accurate collisional rates. We investigate the effects of different sets of hyperfine collisional rates, derived via theÒproportional methodÓ and through direct recoupling calculations. Through an extensive parameter sweep over typical low mass star forming conditions, we show the HCN line ratios to be highly variable to optical depth. We also reproduce an observed effect whereby the red-blue asymmetry of the hyperfine lines (an infall signature) switches sense within a single rotational transition.

Three bright molecular line sources in G333 have recently been shown to exhibit signatures of infall. We describe a molecular line radiative transfer modelling process which is required to extract the infall signature from Mopra and Nanten2 data. The observed line profiles differ greatly between individual sources but are reproduced well by variations upon a common unified model where the outflow viewing angle is the most significant difference between the sources. The models and data together suggest that the observed properties of the high-mass star-forming regions such as infall, turbulence, and mass are consistent with scaled-up versions of the low-mass case with turbulent velocities that are supersonic and an order of magnitude larger than those found in low-mass star-forming regions. Using detailed radiative transfer modeling, we show that the G333 cores are essentially undergoing a scaled-up version of low mass star formation. This is an extension of earlier work in that the degree of infall and the chemical abundances are constrained by the RT modeling in a way that is not practical with a standard analysis of observational data. We also find high velocity infall and high infall mass rates, possibly suggesting accelerated collapse due to external pressure. Molecular depletion due to freeze-out onto dust grains in central regions of the cores is suggested by low molecular abundances of several species. Strong evidence for a local enhancement of 13 C-bearing species towards the outflow cloud cores is discussed, consistent with the presence of shocks caused by the supersonic motions within them.