Possible quantum critical behaviour in the (Cr84Re16)100−yVy alloy system, with 0 ≤ y < 14, was investigated using electrical resistivity (ρ), Seebeck coefficient (S), magnetic susceptibility (χ), Hall coefficient (RH), and specific heat (Cp) measurements as a function of temperature (T). Characteristics typically associated with a quantum critical point (QCP) can be observed in the low temperature behaviour of ρ(y), RH(y), χ(y), and γ(y); where γ is the Sommerfeld coefficient determined from least square fits to the low temperature specific heat measurements. Present results provide evidence of the existence of a putative QCP at a critical concentration of yc ≈ 10.5 for the (Cr84Re16)100−yVy alloy system.
Measurements of the temperature (T) dependence of the magnetic susceptibility (χ) and electrical resistance (R) on an antiferromagnetic (AFM) (Cr84Re16)89.6V10.4 alloy are reported in order to probe the existence of quantum critical behaviour (QCB) utilizing static magnetic fields (H) as a tuning parameter. The results indicate that an increase in H suppresses TN in such a way that it varies exponentially with increasing H. R(T) measurements show evidence of possible superconducting (SC) behaviour below 1 K at H = 0 T. These results therefore indicate the coexistence of the AFM and SC phases in the (Cr84Re16)89.6V10.4 alloy.
Rare-earth orthochromites (RCrO3) with orthorhombically distorted perovskite (ABO3) structure exhibit a wealth of magnetic phenomena including temperature-induced magnetization reversal (TMR), spin-reorientation (SR), spin-flipping (SF) and exchange-bias (EB). These occur as a result of magnetic interactions among the cations such as Cr3+–Cr3+, Cr3+–R3+ and R3+–R3+, where R is the rare earth element. In the present work, GdCrO4 samples were prepared using the sol-gel technique. The as-synthesized samples are amorphous in nature. Calcination of the samples at 600 °C for 1 h leads to the formation of the GdCrO4 phase whereas increasing the calcination temperature to 1000 °C for 1 h triggers the decomposition of GdCrO4 into GdCrO3. The role of thermal decomposition of GdCrO4 to GdCrO3 on crystal structure and magnetic transitions are discussed in this paper. Microstructure analyses show that the GdCrO4 powders have an intercalated porous structure that comprises a core-shell like construction with undistinguishable grain boundaries, whereas the morphology of the GdCrO3 demonstrates bulk nature with particles having micrometer size. Magnetization measurements as a function of temperature (M-T) with different probing magnetic fields show the ferromagnetic Curie temperature, (TC), of the GdCrO4 sample to be 24 K. GdCrO3 orders antiferromagnetically with a Néel temperature, TN (Cr), ascribed to the Cr magnetic moment at 171 K. A spin-flip transition (TSF) occurred at 22 K indicating the flipping of Cr3+ and Gd3+ spins and the spin-reorientation (TSR) transition is located at 5 K. The hysteresis loops measured across the transition temperatures validate the magnetic transitions as observed in the M-T curves.
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