Cobalt-substituted nickel–copper ferrite samples having the chemical formula
Ni0.95−xCoxCu0.05Fe2O4,
where x
varies as 0.01, 0.02 and 0.03, were prepared by the standard double sintering ceramic
technique. The formation of the ferrite phase was confirmed by x-ray diffraction (XRD)
studies. Resistivity and thermo-emf variation with temperature were studied in the
temperature range from room temperature to 773 K as a function of cobalt content. As the
cobalt content increases, the resistivity of the ferrites decreases. AC conductivity
measurements made in the frequency range 100 Hz–1 MHz show that conduction in these
ferrites is due to small polaron hopping. The dielectric constant and loss tangent
(tanδ) were measured at room temperature as a function of frequency in the range 20 Hz to
1 MHz. The room-temperature dielectric measurements show dispersion behaviour
with increasing frequency. To understand the conduction mechanism, complex
impedance measurements were carried out. The variation in saturation magnetization
(Ms) with variation of cobalt content is also studied.
Ferrites with the general formula Li 0.5 Ni 0.75−x/2 Cd x/2 Fe 2 O 4 (where x = 0, 0.1, 0.3, 0.5, 0.7 and 0.9) were prepared by the standard double sintering ceramic method. X-ray diffraction analysis confirmed the single phase spinel structure of the samples. The variation of saturation magnetization (M s ) was studied as a function of Cd content. The dielectric constant (ε ) and dielectric loss tangent (tan δ) were measured at room temperature as a function of frequency in the range 100 Hz-1 MHz. These parameters decrease with increasing frequency for all of the samples. The compositional variation of ε and ρ DC show an inverse trend of variation with each other.
The particulate composite materials of ferrite-ferroelectric ceramics viz. nickel-cobalt-copper ferrite (i.e., Ni0.94Co0.01Cu0.05Fe2O4) and barium titanate were synthesized by the double sintering ceramic technique. The presence of constituent phases in the composites was confirmed by x-ray diffraction studies. The average grain size was calculated by using a scanning electron micrograph. The electrical properties such as dc resistivity and thermo-emf were measured as a function of temperature and volume fraction of constituent phases. The ac conductivity was calculated from dielectric data in the frequency range from 100Hzto1MHz. It is concluded that the conduction in the present composites is due to small polarons. The relative dielectric constant measured as a function of applied frequency varies with the variation in the dc resistivity and molar fraction of constituent phases. It shows dispersion in the lower frequency range. The hysteresis behavior was studied to understand the magnetic properties such as saturation magnetization (Ms) and magnetic moment (μB). The static magnetoelectric (ME) voltage coefficient was measured as a function of applied dc magnetic field. It increases first and then falls down with increasing magnetic field. The variation in ME response has been explained in terms of content of ferrite phase, resistivity of composites, and intensity of magnetic field. The maximum ME conversion factor of 637μV∕cmOe was observed for the composite with 30% Ni0.94Co0.01Cu0.05Fe2O4+70% BaTiO3. These composites may be useful as phase shifters, magnetic sensors, cables, etc.
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