Effective science-based management of water resources in large basins requires a qualitative understanding of hydrologic conditions and quantitative measures of the various components of the water budget, including difficult to measure components such as baseflow discharge to streams. Using widely available discharge and continuously collected specific conductance (SC) data, we adapted and applied a long established chemical hydrograph separation approach to quantify daily and representative annual baseflow discharge at 14 streams and rivers at large spatial (> 1000 km 2 watersheds) and temporal (up to 37 years) scales in the Upper Colorado River Basin. On average, annual baseflow was 21-58% of annual stream discharge, 13-45% of discharge during snowmelt, and 40-86% of discharge during low-flow conditions. Results suggest that reservoirs may act to store baseflow discharged to the stream during snowmelt and release that baseflow during low-flow conditions, and that irrigation return flows may contribute to increases in fall baseflow in heavily irrigated watersheds. The chemical hydrograph separation approach, and associated conceptual model defined here provide a basis for the identification of land use, management, and climate effects on baseflow.
[1] Springs and gaining streams are locations where groundwater flow paths naturally converge and discharge as a flow-weighted mixture of water from the contributing aquifer. The age of that water is therefore a good measure of the mean transit time (MTT) of the contributing aquifer. The question examined in this paper is whether tritiogenic helium-3 and tritium ( 3 He trit -3 H) can be used to estimate MTT in these settings. To answer that question two factors must be considered: (1) the loss of 3 He from discharging groundwater as it becomes exposed to the atmosphere, and (2) the accuracy with which MTT can be determined from flow-weighted 3 He trit -3 H concentrations. These concepts were tested at the Fischa-Dagnitz system (springs and emerging stream), which is part of the southern Vienna Basin aquifer. Conducting a gas tracer test, gas exchange coefficients (l) were established for helium-4 (
Gaining streams can provide an integrated signal of relatively large groundwater capture areas. In contrast to the point-specific nature of monitoring wells, gaining streams coalesce multiple flow paths. Impacts on groundwater quality from unconventional gas development may be evaluated at the watershed scale by the sampling of dissolved methane (CH4 ) along such streams. This paper describes a method for using stream CH4 concentrations, along with measurements of groundwater inflow and gas transfer velocity interpreted by 1-D stream transport modeling, to determine groundwater methane fluxes. While dissolved ionic tracers remain in the stream for long distances, the persistence of methane is not well documented. To test this method and evaluate CH4 persistence in a stream, a combined bromide (Br) and CH4 tracer injection was conducted on Nine-Mile Creek, a gaining stream in a gas development area in central Utah. A 35% gain in streamflow was determined from dilution of the Br tracer. The injected CH4 resulted in a fivefold increase in stream CH4 immediately below the injection site. CH4 and δ(13) CCH4 sampling showed it was not immediately lost to the atmosphere, but remained in the stream for more than 2000 m. A 1-D stream transport model simulating the decline in CH4 yielded an apparent gas transfer velocity of 4.5 m/d, describing the rate of loss to the atmosphere (possibly including some microbial consumption). The transport model was then calibrated to background stream CH4 in Nine-Mile Creek (prior to CH4 injection) in order to evaluate groundwater CH4 contributions. The total estimated CH4 load discharging to the stream along the study reach was 190 g/d, although using geochemical fingerprinting to determine its source was beyond the scope of the current study. This demonstrates the utility of stream-gas sampling as a reconnaissance tool for evaluating both natural and anthropogenic CH4 leakage from gas reservoirs into groundwater and surface water.
Models need not be complex to be useful. An existing groundwater-flow model of Salt Lake Valley, Utah, was adapted for use with convolution-based advective particle tracking to explain broad spatial trends in dissolved solids. This model supports the hypothesis that water produced from wells is increasingly younger with higher proportions of surface sources as pumping changes in the basin over time. At individual wells, however, predicting specific water-quality changes remains challenging. The influence of pumping-induced transient groundwater flow on changes in mean age and source areas is significant. Mean age and source areas were mapped across the model domain to extend the results from observation wells to the entire aquifer to see where changes in concentrations of dissolved solids are expected to occur. The timing of these changes depends on accurate estimates of groundwater velocity. Calibration to tritium concentrations was used to estimate effective porosity and improve correlation between source area changes, age changes, and measured dissolved solids trends. Uncertainty in the model is due in part to spatial and temporal variations in tracer inputs, estimated tracer transport parameters, and in pumping stresses at sampling points. For tracers such as tritium, the presence of two-limbed input curves can be problematic because a single concentration can be associated with multiple disparate travel times. These shortcomings can be ameliorated by adding hydrologic and geologic detail to the model and by adding additional calibration data. However, the Salt Lake Valley model is useful even without such small-scale detail.
Many basins throughout the world have sparse hydrologic and geologic data, but have increasing demands for water and a commensurate need for integrated understanding of surface and groundwater resources. This paper demonstrates a methodology for using a distributed parameter water-balance model, gaged surface-water flow, and a reconnaissance-level groundwater flow model to develop a first-order water balance. Flow amounts are rounded to the nearest 5 million cubic meters per year. <br><br> The San Diego River basin is 1 of 5 major drainage basins that drain to the San Diego coastal plain, the source of public water supply for the San Diego area. The distributed parameter water-balance model (Basin Characterization Model) was run at a monthly timestep for 1940–2009 to determine a median annual total water inflow of 120 million cubic meters per year for the San Diego region. The model was also run specifically for the San Diego River basin for 1982–2009 to provide constraints to model calibration and to evaluate the proportion of inflow that becomes groundwater discharge, resulting in a median annual total water inflow of 50 million cubic meters per year. On the basis of flow records for the San Diego River at Fashion Valley (US Geological Survey gaging station 11023000), when corrected for upper basin reservoir storage and imported water, the total is 30 million cubic meters per year. The difference between these two flow quantities defines the annual groundwater outflow from the San Diego River basin at 20 million cubic meters per year. These three flow components constitute a first-order water budget estimate for the San Diego River basin. The ratio of surface-water outflow and groundwater outflow to total water inflow are 0.6 and 0.4, respectively. Using total water inflow determined using the Basin Characterization Model for the entire San Diego region and the 0.4 partitioning factor, groundwater outflow from the San Diego region, through the coastal plain aquifer to the Pacific Ocean, is calculated to be approximately 50 million cubic meters per year. <br><br> The area-scale assessment of water resources highlights several hydrologic features of the San Diego region. Groundwater recharge is episodic; the Basin Characterization Model output shows that 90 percent of simulated recharge occurred during 3 percent of the 1982–2009 period. The groundwater aquifer may also be quite permeable. A reconnaissance-level groundwater flow model for the San Diego River basin was used to check the water budget estimates, and the basic interaction of the surface-water and groundwater system, and the flow values, were found to be reasonable. Horizontal hydraulic conductivity values of the volcanic and metavolcanic bedrock in San Diego region range from 1 to 10 m per day. Overall, results establish an initial hydrologic assessment formulated on the basis of sparse hydrologic data. The described flow variability, extrapolation, and unique characteristics represent a realistic view of current (2012) hydrolo...
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