Mechanical and optical properties
of polycarbonate (PC) containing p-terphenyl (p-tPh) are studied. It is found from the dynamic mechanical
spectra that the addition of p-tPh greatly enhances
the modulus in the glassy state due to the antiplasticizing effect.
Moreover, p-tPh molecules dissolved in PC show marked
intermolecular orientation correlation with PC chains during hot-stretching.
As a result, p-tPh orients to the stretching direction
accompanying the orientation of PC chains. Because p-tPh shows a high level of optical anisotropy, the oriented p-tPh molecules enhance the orientation birefringence. The
enhancement of both modulus and optical anisotropy leads to a thinner
retardation film, which will be a great benefit in the industry.
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