A light-harvesting (LH) antenna complex II, LHCII, isolated from spinach was immobilized onto an indium tin oxide (ITO) electrode with dot patterning of 3-aminopropyltriethoxysilane (APS) by utilizing electrostatic interactions between the cationic surface of the electrode and the anionic surface of stromal side of the LHCII polypeptide. Interestingly, the illumination of LHCII assembled onto the ITO electrode produced a photocurrent response that depends on the wavelength of the excitation light. Further, LHCII was immobilized onto a TiO 2 nanostructured film to extend for the development of a dye-sensitized biosolar cell system. The photocurrent measured in the iodide/tri-iodide redox system of an ionic liquid based electrolyte on the TiO 2 system showed remarkable enhancement of the conversion efficiency, as compared to that on the ITO electrode.
Light-harvesting antenna core (LH1-RC) complexes isolated from Rhodospirillum rubrum and Rhodopseudomonas palustris were successfully self-assembled on an ITO electrode modified with 3-aminopropyltriethoxysilane. Near infra-red (NIR) absorption, fluorescence, and IR spectra of these LH1-RC complexes indicated that these LH1-RC complexes on the electrode were stable on the electrode. An efficient energy transfer and photocurrent responses of these LH1-RC complexes on the electrode were observed upon illumination of the LH1 complex at 880 nm.
The Myojin Knoll is a submarine volcano that has a classically beautiful conical-shaped silicic caldera whose surface is covered by pumice. To determine the tectonic structure inside the caldera wall and beneath the caldera floor of this pumicious submarine volcano, we carried out a structural interpretation study using newly collected deep-penetrating multichannel seismic (MCS) reflection data. We also conducted a detailed velocity analysis of the MCS data, which facilitated the interpretation study. The results demonstrate that approximately 90% of the caldera wall is composed of pumiceous volcanic breccia. This finding supports those of previous researchers who, based on seafloor observations, single-channel seismic reflection, and gravity and geomagnetic data, concluded the Myojin Knoll is a knoll having a pumiceous caldera wall underlain by a pre-caldera rhyolitic stratovolcano edifice. We also determined a down-warping reflector approximately 800 m beneath the caldera floor. A seismic unit immediately above the reflector has a higher P-wave velocity than the pumice units and shows a chaotic seismic reflection pattern. We interpreted the reflector to be the bottom of a possible shallow magma chamber where the magma would undergo repeated expansion and contraction as a result of recurrent eruption activities.
Photoinduced hydrogen production via the photoreduction of methyl viologen (MV2+) using the sensitization of light-harvesting chlorophyll a/b–protein complex of photosystem II (LHCII) from spinach in the presence of platinum nanoparticles and NADH is developed.
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