No abstract

No abstract

No abstract

This study investigates the potential application of the polyethyleneimine- (PEI) and amidoxime-modified Spirulina (Arthrospira) platensis biomasses for the removal of uranium ion in batch mode using the native biomass as a control system. The uranium ion adsorption was also characterized by attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectra, zeta potential analysis, and surface area measurement studies. The effects of pH, biomass amount, contact time, initial uranium ion concentration, and ionic strength were evaluated by using native and modified algal biomass preparations. The uranium ion removal was rapid, with more than 70% of total adsorption taking place in 40 min, and equilibrium was established within 60 min. From the experimental data, it was found that the amount of adsorption uranium ion on the algal preparations decreased in the following series: amidoxime-modified algal biomass > PEI-modified algal biomass > native algal biomass. Maximum adsorption capacities of amidoxime- and PEI-modified, and native algal biomasses were found to be 366.8, 279.5, and 194.6 mg/g, respectively, in batchwise studies. The adsorption rate of U(VI) ion by amidoxime-modified algal biomass was higher than those of the native and PEI-modified counterparts. The adsorption processes on all the algal biomass preparations followed by the Dubinin-Radushkevitch (D-R) and Temkin isotherms and pseudo-second-order kinetic models. The thermodynamic parameters were determined at four different temperatures (i.e., 15, 25, 35, and 45 °C) using the thermodynamics constant of the Temkin isotherm model. The ΔH° and ΔG° values of U(VI) ion adsorption on algal preparations show endothermic heat of adsorption; higher temperatures favor the process. The native and modified algal biomass preparations were regenerated using 10 mM HNO3. These results show that amidoxime-modified algal biomass can be a potential candidate for effective removal of U(VI) ion from aqueous solution.

The thermodynamic studies indicated that the biosorption process was spontaneous and endothermic in nature under studied conditions. For all the tested biosorbents, biosorption kinetic was best described by the pseudo-second-order model.

The sediment of Lake Çubuk in NW Anatolia, which is situated very close to the climate boundary between the dry Central Anatolia and the wet Marmara region, is regarded as a suitable climate archive to test inward and outward movements of this boundary in accordance with past climate variations. Herein, we study the stratigraphic record of the last 2800 years of this landslide-dammed lake at 1030 m elevation, using multi-proxy tools (sedimentology, major and trace element geochemistry, stable isotopes, pollen, diatoms and ostracods) and compare the results with other contemporaneous Anatolian climatic records. Our findings indicate that Lake Çubuk recorded seven distinct climatic periods in the last 2800 years that have been previously revealed elsewhere in Anatolia. The most arid period occurred at the end of the Near-East Aridification Phase at approximately 200 BC when the δ 18 O shifted to very negative values, and the planktonic diatom ratio considerably decreased. The Dark Ages and the late Byzantine periods between AD 670 and 1070 are characterized by more positive δ 18 O values, increasingly higher lake levels and the most extensive arboreal cover of the entire record. The 'Little Ice Age' appeared suddenly, within 40 years, at AD 1350 and is reflected in all of the proxies, including a positive shift in δ 18 O, a sharp decrease in pollen of shrub and herb to the benefit of pine trees and a rapid increase in benthic diatom abundance indicating a lake level shallowing. In many parts of the record, a close match between the stable isotopes and the pollen assemblage zones in the last 2800 years demonstrates that climate rather than human activity was the primary driver of vegetation cover in this mid-altitude mountain of NW Anatolia.

No abstract

The accumulation of heavy metals such as Pb, Hg, Co, Cr, Cu, Zn, and Br were determined in water, sediment, muscle, and gill of three fish species (Leuciscus cephalus, Capoeta tinca, Capoeta capoeta) which were collected in Kizilirmak River Basin (Delice River). The metal concentration showed a general trend of Br>Zn>Pb>Cr>Cu>Hg>Co in water and Cr>Zn>Pb>Cu>Co>Hg>Br in sediment samples while Zn>Cu>Pb>Br>Cr>Hg>Co were in muscle and Zn>Pb>Cu>Cr>Br>Hg>Co were in the gill tissue.