Oceanic core complexes (OCCs) represent tectonic windows into the oceanic lower crust and mantle; they are key structures in understanding the tectono-magmatic processes shaping the oceanic lithosphere. We present a petrological and geochemical study of gabbros collected at the Mado Megamullion, a recently discovered OCC located in the extinct Shikoku back-arc basin. Bathymetry of the Mado Megamullion reveals spreading-parallel corrugations extending 25 km from the breakaway to the termination. Samples from several locations include peridotites, gabbros, dolerite, and rare pillow basalts. Gabbros range from granular to varitextured olivine gabbros and oxide gabbros. The emplacement of these gabbroic rocks within the oceanic lithosphere was followed by a multiphase tectono-metamorphic evolution including (i) dynamic recrystallization within shear zones, developed under granulite-to upper-amphibolite-facies conditions, and (ii) intrusion of highly evolved melts forming felsic segregations. This tectono-metamorphic evolution recalls that of the lower crust from other OCCs worldwide, demonstrating that this OCC exposes deep-seated intrusions progressively exhumed by detachment faulting. Nonetheless, the Mado Megamullion lower crustal gabbros show an unusual crystal line of descent, different from what is reported from mid-ocean ridge lower crustal rocks. We infer that the water-bearing character of the primary melts in this back-arc basin triggered the early precipitation of clinopyroxene, soon followed by amphibole and Fe-Ti oxides. Such modifications in phase saturation are likely to be directly related to the back-arc setting of the Mado Megamullion. If so, the phase assemblages of oceanic gabbros may be a diagnostic for the tectonic setting of lower crustal rocks in ophiolites.

We present the whole-rock and the mineral chemical data for upper mantle peridotites from the Harmancık region in NW Turkey and discuss their petrogenetic-tectonic origin. These peridotites are part of a Tethyan ophiolite belt occurring along the İzmir-Ankara-Ercincan suture zone in northern Turkey, and include depleted lherzolites and refractory harzburgites. The Al 2 O 3 contents in orthopyroxene and clinopyroxene from the depleted lherzolite are high, and the Cr-number in the coexisting spinel is low falling within the abyssal field. However, the orthopyroxene and clinopyroxene in the harzburgites have lower Al 2 O 3 contents for a given Cr-number of spinel, and plot within the lower end of the abyssal field. The whole-rock geochemical and the mineral chemistry data imply that the Harmancık peridotites formed by different degrees of partial melting (~%10-27) of the mantle. The depleted lherzolite samples have higher MREE and HREE abundances than the harzburgitic peridotites, showing convex-downward patterns. These peridotites represent up to ~16 % melting residue that formed during the initial seafloor spreading stage of the Northern Neotethys. On the other hand, the more refractory harzburgites represent residues after ~4-11 % hydrous partial melting of the previously depleted MOR mantle, which was metasomatized by slab-derived fluids during the early stages of subduction. The Harmancık peridotites, hence, represent the fragments of upper mantle rocks that formed during different stages of the tectonic evolution of the Tethyan oceanic lithosphere in Northern Neotethys. We infer that the multi-stage melting history of the Harmancık peridotites reflect the geochemically heterogeneous character of the Tethyan oceanic lithosphere currently exposed along the İzmir-Ankara-Erzincan suture zone.

We determined the mineralogical and petrological characteristics of ultramafic rocks dredged from two oceanic core complexes: the Mado Megamullion and 23 30 0 N non-transform offset massif, which are located within the Shikoku back-arc basin in the Philippine Sea. The ultramafic rocks are strongly serpentinized, but can be classified as harzburgite/lherzolite or dunite, based on relict primary minerals and their pseudomorphs. Strongly elongated pyroxene porphyroclasts with undulatory extinction indicate high-temperature (≥700 C) strain localization on a detachment fault within the upper mantle at depths below the brittle-viscous transition. During exhumation, the peridotites underwent impregnation by magmatic or hydrothermal fluids, lizardite/chrysotile serpentinization at ≤300 C, antigorite crystallization, and silica metasomatism that formed talc. These features indicate that the detachment fault zones formed a fluid pathway and facilitated a range of fluid-peridotite interactions.

The Khetri Copper Belt (KCB), a part of the Proterozoic Delhi-Aravalli fold belt in western India, hosts several Cu deposits, which are known to contain considerable Au, Ag, Co and Ni. Although many Cobearing phases have been reported from the KCB and adjacent areas, detailed textural and geochemical data are either unavailable or scant except for mackinawite. In this study, we describe the textures and compositions (determined by EPMA) of two very rare Co-rich phases, namely cobaltian mackinawite (containing up to 12.68 wt.% Co, 1.90 wt.% Ni and 2.52 wt.% Cu) and cobalt-pentlandite (containing up to 49.30 wt.% Co and 10.19 wt.% Ni), identified based on composition, from the Madan-Kudan deposit. To the best of our knowledge, neither cobalt-pentlandite nor such highly Co-rich mackinawite have previously been reported from this area. The common sulphide minerals viz. chalcopyrite, pyrrhotite and rare pyrite occur in chalcopyrite-pyrrhotite ± pyrite-magnetite-chlorite-blue amphibole (Cl-rich hastingsitepargasite-sadanagaite) ± marialitic scapolite ± allanite ± uraninite veins in amphibole-bearing feldspathic quartzite and garnetiferous chlorite schist. Cobaltian mackinawite is invariably associated with chalcopyrite and occurs as exsolution and inclusion within chalcopyrite or outside, but at the contact of chalcopyrite. On the other hand, cobalt-pentlandite is invariably associated with pyrrhotite and shows similar textural relation with pyrrhotite as that of mackinawite with chalcopyrite. Mineralogically diverse undeformed sulphide veins comprising Cl-rich amphibole and locally Cl-rich marialitic scapolite suggests epigenetic hydrothermal mineralization involving Cl-rich saline fluid in the Madan-Kudan deposit. Transport of metals, derived from a mafic source rock with high intrinsic Ni:Co ratio, by Cl-rich fluid can suitably explain the high Co:Ni ratio of the studied ore minerals. Presence of such highly Co-rich phases and other circumstantial evidences, enumerated in this work, are consistent with variants of Fe oxide (-Cu-Au) (IOCG) style mineralization, at least for some stages of mineralization in the Madan-Kudan deposit.

This paper explores the evolutional process of back-arc basin (BAB) magma system at final spreading stage of extinct BAB, Shikoku Basin (Philippine Sea) and assesses its tectonic evolution using a newly discovered oceanic core complex, the Mado Megamullion. Bulk and in-situ chemical compositions together with in-situ Pb isotope composition of dolerite, oxide gabbro, gabbro, olivine gabbro, dunite, and peridotite are presented. Compositional ranges and trends of the igneous and peridotitic rocks from the Mado Megamullion are similar to those from the slow- to ultraslow-spreading mid-ocean ridges (MOR). Since the timing of the Mado Megamullion exhumation corresponds to the very end of the Shikoku Basin opening, the magma supply was subdued and highly episodic, leading to extreme magma differentiation to form ferrobasaltic, hydrous magmas. In-situ Pb isotope composition of magmatic brown amphibole in the oxide gabbro is identical to that of depleted source mantle for mid-ocean ridge basalt (MORB). In the context of hydrous BAB magma genesis, the magmatic water was derived solely from the MORB source mantle. The distance from the back-arc spreading center to the arc front increased away through maturing of the Shikoku Basin to cause MORB-like magmatism. After the exhumation of Mado Megamullion along detachment faults, dolerite dikes intruded as a post-spreading magmatism. The final magmatism along with post-spreading Kinan Seamount Chain volcanism were introduced around the extinct back-arc spreading center after the opening of Shikoku Basin by residual mantle upwelling.