Monodisperse single/few-layered MoSe2 nanocrystals are directly deposited onto conducting substrates, through electrochemical exfoliation of bulk MoSe2, which exhibit remarkable electrocatalytic activity for the hydrogen evolution reaction.
Transition-metal dichalcogenide quantum dots (TMDQDs) with few layers are in the forefront of recent research on tailored 2D layered materials owing to their unique band structure. Such quantum dots (QDs) draw wide interest as potential candidates for components in optoelectronic devices. Although a few attempts towards single step synthesis of MoS QDs have been demonstrated, limited methods are available for WS QDs. Herein, we demonstrate a one-step electrochemical synthesis of luminescent WS QDs from their bulk material. This is achieved by a synergistic effect of perchlorate intercalation in non-aqueous electrolyte and the applied electric field. The average size of the WS QDs is 3 ±1 nm (N=102) with few layers. The QDs show a higher photoluminescence (PL) quantum efficiency (5 %) and exhibit an excitation wavelength-dependent photoluminescence. This unprecedented electrochemical avenue offers a strategy to synthesize size tunable WS nanostructures, which have been systematically investigated by various characterization techniques such as transmission electron microscopy (TEM), photoluminescence and UV/Vis spectroscopies, and X-ray diffraction (XRD). Time-dependent TEM investigations revealed that time plays a vital role in this electrochemical transformation. This electrochemical transformation provides a facile method to obtain WS QDs from their bulk counterpart, which is expected to have a greater impact on the design and development of nanostructures derived from 2D materials.
Phosphorene has attracted great interest
in the rapidly emerging field of two-dimensional layered nanomaterials.
Recent studies show promising electrocatalytic activity of few-layered
phosphorene sheets toward the oxygen evolution reaction (OER). However,
controllable synthesis of mono/few-layered phosphorene nanostructures
with a large number of electrocatalytically active sites and exposed
surface area is important to achieve significant enhancement in OER
activity. Here, a novel strategy for controlled synthesis and in situ surface functionalization of phosphorene quantum
dots (PQDs) using a single-step electrochemical exfoliation process
is demonstrated. Phosphorene quantum dots functionalized with nitrogen-containing
groups (FPQDs) exhibit efficient and stable electrocatalytic activity
for OER with an overpotential of 1.66 V @ 10 mA cm–2, a low Tafel slope of 48 mV dec–1, and excellent
stability. Further, we observe enhanced electron transfer kinetics
for FPQDs toward the Fe2+/Fe3+ redox probe in
comparison with pristine PQDs. The results demonstrate the promising
potential of phosphorene as technologically viable OER electrodes
for water-splitting devices.
Electrochemical valorization of biomass waste (e.g., glycerol) for production of value‐added products (such as formic acid) in parallel with hydrogen production holds great potential for developing renewable and clean energy sources. Here, a synergistic effort between theoretical calculations at the atomic level and experiments to predict and validate a promising oxide catalyst for the glycerol oxidation reaction (GOR) are reported, providing a good example of designing novel, cost‐effective, and highly efficient electrocatalysts for producing value‐added products at the anode and high‐purity hydrogen at the cathode. The predicted CoMoO4 catalyst is experimentally validated as a suitable catalyst for GOR and found to perform best among the investigated metal (Mn, Co, Ni) molybdate counterparts. The potential required to reach 10 mA cm−2 is 1.105 V at 60 °C in an electrolyte of 1.0 m KOH with 0.1 m glycerol, which is 314 mV lower than for oxygen evolution. The GOR reaction pathway and mechanism based on this CoMoO4 catalyst are revealed by high‐performance liquid chromatography and in situ Raman analysis. The coupled quantitative analysis indicates that the CoMoO4 catalyst is highly active toward CC cleavage, thus presenting a high selectivity (92%) and Faradaic efficiency (90%) for formate production.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.