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We investigate the kinetics of bromination of malonic acid, bromomalonic acid, tartronic acid, and ethanetetracarboxylic acid in 1 M sulfuric acid with bromine and hypobromous acid as brominating agents. In all cases the reaction occurs via the enol form of the acid, and the reaction products are brominated species. The possibility of bromide production in the reaction of malonic acid or bromomalonic acid with hypobromous acid can be ruled out. These results are important for the negative feedback loop in the Belousov−Zhabotinsky reaction.

Applying combined HPLC and NMR techniques, it was found that, besides the already known 1,1,2,2-ethanetetracarboxylic acid (ETA), monomalonyl malonate (MAMA) is also a product of the Ce4+−malonic acid reaction. This is indirect evidence that two different types of organic radicals are formed in the reaction:  the alkyl and the carboxylato malonyl radicals. While ETA is a recombination product of two alkyl radicals, MAMA is formed in the recombination of one alkyl and one carboxylato radical.

Temporal oscillations of the cerium(IV)-catalysed Belousov-Zhabotinsky reaction under addition of various Brconcentrations are investigated. The relationship between the induction period and Brconcentration, which is a controlling species in the BZ oscillating reaction, is reported. The oscillations of the Ce(IV) catalyst are followed by using UV-Vis spectrophotometric methods under closed batch and oxygen free systems. Experimental observations demonstrate that increasing Brconcentration decreases the induction period exponentially, whereas it increases the oscillation period linearly. The results reveal that the oscillations without induction period are observed by the addition of 1.0 × 10 −2 M Brconcentration. Addition of Brinto the BZ solution mainly involves the process A of the FKN mechanism. Numerical results reveal that the addition of Brincreases the production of BrMA, but decreases the induction period.

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