In the study of chaotic behavior, Lyapunov exponents play an important part. In this paper, we demonstrate how the Lyapunov exponents close to zero of a system of many hard spheres can be described as Goldstone modes, by using a Boltzmann type of approach. At low densities, the correct form is found for the wave number dependence of the exponents as well as for the corresponding eigenvectors in tangent space. The predicted values for the Lyapunov exponents belonging to the transverse mode are within a few percent of the values found in recent simulations, the propagation velocity for the longitudinal mode is within 1%, but the value for the Lyapunov exponent belonging to the longitudinal mode deviates from the simulations by 30%. For higher densities, the predicted values deviate more from the values calculated in the simulations. These deviations may be due to contributions from ring collisions and similar terms, which, even at low densities, can contribute to the leading order.

We show that macroscopic nonintegrable lattices of spins 1/2, which are often considered to be chaotic, do not exhibit the basic property of classical chaotic systems, namely, exponential sensitivity to small perturbations. We compare chaotic lattices of classical spins and nonintegrable lattices of spins 1/2 in terms of their magnetization responses to an imperfect reversal of spin dynamics known as Loschmidt echo. In the classical case, magnetization is exponentially sensitive to small perturbations with a characteristic exponent equal to twice the value of the largest Lyapunov exponent of the system. In the case of spins 1/2, magnetization is only power-law sensitive to small perturbations.

The scaling of friction with the contact size A and (in)commensurabilty of nanoscopic and mesoscopic crystals on a regular substrate are investigated analytically for triangular nanocrystals on hexagonal substrates. The crystals are assumed to be stiff, but not completely rigid. Commensurate and incommensurate configurations are identified systematically. It is shown that three distinct friction branches coexist, an incommensurate one that does not scale with the contact size (A 0 ) and two commensurate ones which scale differently (with A 1/2 and A) and are associated with various combinations of commensurate and incommensurate lattice parameters and orientations. This coexistence is a direct consequence of the two-dimensional nature of the contact layer, and such multiplicity exists in all geometries consisting of regular lattices. To demonstrate this, the procedure is repeated for rectangular geometry. The scaling of irregularly shaped crystals is also considered, and again three branches are found (A 1/4 ,A 3/4 ,A). Based on the scaling properties, a quantity is defined which can be used to classify commensurability in infinite as well as finite contacts. Finally, the consequences for friction experiments on gold nanocrystals on graphite are discussed.

Recent AFM experiments have shown that the low-friction sliding of incommensurate graphite flakes on graphite can be destroyed by torque-induced rotations. Here we theoretically investigate the stability of superlubric sliding against rotations of the flake. We find that the occurrence of superlubric motion critically depends on the physical parameters and on the experimental conditions: particular scan lines, thermal fluctuations and high loading forces can destroy the stability of superlubric orbits. We find that the optimal conditions to achieve superlubric sliding are given by large flakes, low temperature, and low loads, as well as scanning velocities higher than those used in AFM experiments.