We present the case of degradation of organic solar cells by sunlight concentrated to a moderate level (∼4 suns). This concentration level is not enough for sufficient acceleration of the photobleaching or trap‐generation in the photoactive layer and therefore such short treatment (100 minutes) does not affect the short‐circuit current of the device. However, a significant degradation of VOC and FF has been recorded by measurements of the cell current‐voltage curves with a variation of light intensity, for the devices before and after the treatment. The same degradation was found to occur after short application of forward voltage biases in the dark. This kind of degradation is found to be repairable, and could even be prevented by simple electrical treatment (short pulses of the reverse bias). Moreover, even the fresh cells can be improved by the same process. Generation and degeneration of shunts in ZnO hole‐blocking layer as underlying physical mechanisms for the cell degradation and restoration, respectively, can explain the results.

For decades, progress in the field of optical (including solar) energy conversion was dominated by advances in the conventional concentrating optics and materials design. In recent years, however, conceptual and technological breakthroughs in the fields of nanophotonics and plasmonics combined with better understanding of the thermodynamics of the photon energy conversion processes re-shaped the landscape of energy conversion schemes and devices. Nanostructured devices and materials that make use of size quantization effects to manipulate photon density of states offer a way to overcome the conventional light absorption limits. Novel optical spectrum splitting and photon recycling schemes reduce the entropy production in the optical energy conversion platforms and boost their efficiencies. Optical design concepts are rapidly expanding into the infrared energy band, offering new approaches to harvest waste heat, reduce the thermal emission losses, and achieve non-contact radiative cooling of solar cells as well as of optical and electronic circuitry. Light-matter interaction enabled by nanophotonics and plasmonics underlie the performance of the third-and fourth-generation energy conversion devices, including up-and downconversion of photon energy, near-field radiative energy transfer, and hot electron generation and harvesting. Finally, the increased market penetration of alternative solar energy conversion technologies amplifies the role of cost-driven and environmental considerations.This roadmap on optical energy conversion provides a snapshot of the state-of-the art in optical energy conversion, remaining challenges, and most promising approaches to address these challenges. Leading experts authored 19 focused short sections of the roadmap, where they share their vision on a specific aspect of this burgeoning research field. The roadmap opens up with a tutorial section, which introduces major concepts and terminology. It is our hope that the roadmap will serve as an important resource for the scientific community, new generations of researchers, funding agencies, industry experts and investors.

A large number of flexible polymer solar modules comprising 16 serially connected individual cells was prepared at the experimental workshop at Risø DTU. The photoactive layer was prepared from several varieties of P3HT (Merck, Plextronics, BASF and Risø DTU) and two varieties of ZnO (nanoparticulate, thin film) were employed as electron transport layers. The devices were all tested at Risø DTU and the functional devices were subjected to an inter-laboratory study involving the performance and the stability of modules over time in the dark, under light soaking and outdoor conditions. 24 laboratories from 10 countries and across four different continents were involved in the studies. The reported results allowed for analysis of the variability between different groups in performing lifetime studies as well as performing a comparison of different testing procedures. These studies constitute the first steps toward establishing standard procedures for an OPV lifetime charac terization

It is widely accepted that efficiency of organic solar cells could be limited by their size. However, the published data on this effect are very limited and none of them includes analysis of light intensity dependence of the key cell parameters. We report such analysis for bulk heterojunction solar cells of various sizes and suggest that the origin of both the size and the light intensity effects should include underlying physical mechanisms other than conventional series resistance dissipation. In particular, we conclude that the distributed nature of the ITO resistance and its influence on the voltage dependence of photocurrent and dark current is the key to understanding size limitation of the organic photovoltaics (OPV) efficiency. Practical methods to overcome this limitation as well as the possibility of producing concentrator OPV cells operating under sunlight concentrations higher than 10 suns are discussed.

No abstract