Pervaporation (PV) has shown great promise in water desalination technology. In this work, laponite XLG-Poly (vinyl alcohol) (PVA-Lap) mixed matrix membranes (MMMs) were fabricated to investigate the elaboration of desalination of high-salinity water by pervaporation. The influence of laponite content on the morphology, chemical structure and hydrophilicity of the membranes was investigated. In addition, salt transport properties in the membranes were observed. Moreover, the effect of different laponite content in the PVA matrix on the desalination performance was observed at temperatures from 40°C to 70 °C and feed solutions with up to 10 wt% NaCl. The prepared MMMs showed higher hydrophilicity and roughness of the surface and higher mechanical stability. The higher water flux of 58.6 kg/m 2 .h with a salt rejection over 99.9 % was achieved using 2 wt% laponite XLG MMMs desalinating 3 wt% aqueous NaCl solution at 70 °C. The salt permeability in the membrane was lower by two orders of magnitude than that of water. The water/salt selectivity increased, while the water permeability decreased, with increasing of laponite content in the membrane.

Chemical process design is a creative step of engineers that should be supported by different computer-aided design tools. Such tools should be simple and easy to use because process synthesis often means the investigation of a huge number of alternatives. During the design of the separation of liquid mixtures, among many others, distillation and pervaporation are usually simultaneously considered because pervaporation is frequently considered as an alternative to distillation. To easily compare the efficiencies of continuous pervaporation and flash distillation, we propose a new and simple method, the so-called membrane flash index (MFLI). The comparison is based upon vapor–liquid equilibrium data and the permeation data of a pervaporation membrane and therefore can be plotted on a common chart in the case of binary mixtures. The permeation values of organophilic and hydrophilic pervaporations can be calculated with the help of known separation factors and feed concentrations. The MFLI is dimensionless and can be determined by dividing the permeate concentration by the corresponding vapor equilibrium data obtained from a simple flash distillation. Only the feed concentration, separation factor, and refereed equilibrium data are necessary for the calculations. If the MFLI is <1, the application of pervaporation can be worse than that of flash distillation. In our study, the efficiencies of pervaporation and flash distillation are compared using three mixtures, methanol/water, ethanol/water, and isobutanol/water. After determining the MFLI for different types of membranes, we can conclude that the separation capability of hydrophilic membranes is significantly better than that of the organophilic ones and also better than that of flash distillation by far. Apart from azeotrope braking, the MFLI, as a single number, gives clear information about the separation capabilities of pervaporation and flash distillation in the course of process design.

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Perfluorosulfonic acid (PFSA) polymers such as Nafion are the most frequently used Proton Exchange Membrane (PEM) in PEM fuel cells. Nafion XL is one of the most recently developed membranes designed to enhance performance by employing a mechanically reinforced layer in the architecture and a chemical stabilizer. The influence of the water and acid pre-treatment process on the physicochemical properties of Nafion XL membrane and Membrane Electrode Assembly (MEA) was investigated. The obtained results indicate that the pre-treated membranes have higher water uptake and dimensional swelling ratios, i.e., higher hydrophilicity, while the untreated membrane demonstrated a higher ionic exchange capacity. Furthermore, the conductivity of the acid pre-treated Nafion XL membrane was ~9.7% higher compared to the untreated membrane. Additionally, the maximum power densities obtained at 80 °C using acid pre-treatment were ~0.8 and 0.93 W/cm2 for re-cast Nafion and Nafion XL, respectively. However, the maximum generated powers for untreated membranes at the same condition were 0.36 and 0.66 W/cm2 for re-cast Nafion and Nafion XL, respectively. The overall results indicated that the PEM’s pre-treatment process is essential to enhance performance.