Production from organic-rich shale petroleum systems is extremely challenging due to the complex rock and flow characteristics. An accurate characterization of shale reservoir rock properties would positively impact hydrocarbon exploration and production planning. We integrate large-scale geologic components with small-scale petrophysical rock properties to categorize distinct rock types in low-porosity and low-permeability shales. We then use this workflow to distinguish three rock types in the reservoir interval of the Niobrara Shale in the Denver Basin of the United States: the Upper Chalks (A, B, and C Chalk), the Marls (A, B, and C Marl), and the Lower Chalks (D Chalk and Fort Hays Limestone). In our study area, we find that the Upper Chalk has better reservoir-rock quality, moderate source-rock potential, stiffer rocks, and a higher fraction of compliant micro- and nanopores. On the other hand, the Marls have moderate reservoir-rock quality and a higher source-rock potential. The Upper Chalks and the Marls should have major economic potential. The Lower Chalk has higher porosity and a higher fraction of micro- and nanopores; however, it exhibits poor source-rock potential. The measured core data indicate large mineralogy, organic richness, and porosity heterogeneities throughout the Niobrara interval at all scales.
This paper assesses the pore- and field-scale enhanced oil recovery (EOR) mechanisms by gas injection for low permeability shale reservoirs. We performed compression-decompression laboratory experiments in ultratight outcrop cores of the Permian Basin as well as in ceramic cores using n-dodecane for oil. The EOR assessment strategy involved determining the quantity of oil produced after injection of helium (He), nitrogen (N2), methane (CH4), and methane/carbon dioxide (CH4/CO2) gas mixtures into unfractured and fractured cores followed by depressurization. Using the oil recovery volumes from cores with different number of fractures, we quantified the effect of fractures on oil recovery—both for Wolfcamp outcrop cores and several ceramic cores. We observed that the amount of oil recovered was significantly affected by the pore-network complexity and pore-size distribution. We conducted laboratory EOR tests at pore pressure of 1500 psia and temperature of 160°F using a unique coreflooding apparatus capable of measuring small volumes of the effluent oil less than 1 cm3. The laboratory procedure consisted of (1) injecting pure n-dodecane (n-C12H26) into a vessel containing a core which had been moistened hygroscopically and vacuumed, and raising and maintaining pressure at 1500 psia for several days or weeks to saturate the core with n-dodecane; (2) dropping the vessel pressure and temperature to laboratory ambient conditions to determine how much oil had entered the core; (3) injecting gas into the n-dodecane saturated core at 1500 psia for several days or weeks; (4) shutting in the core flooding system for several days or weeks to allow gas in the fractures to interact with the matrix oil; (5) finally, producing the EOR oil by depressurization to room pressure and temperature. Thus, the gas injection EOR is a ‘huff-and-puff’ process. The primary expansion-drive oil production with no dissolved gas from fractured Wolfcamp cores was 5% of the initial oil in place (IOIP) and 3.6% of IOIP in stacked synthetic cores. After injecting CH4/CO2 gas mixtures, the EOR oil recovery by expansion-drive in Wolfcamp core was 12% of IOIP and 8.2% of IOIP in stacked synthetic cores. It is to be noted that the volume of the produced oil from Wolfcamp cores was 0.27 cm3 while it was 6.98 cm3 in stacked synthetic cores. Thus, while synthetic cores do not necessarily represent shale reservoir cores under expansion drive and gas-injection EOR, these experiments provide a means to quantify the oil recovery mechanism of expansion-drive in shale reservoirs. The gas injection EOR oil recovery in Wolfcamp cores with no fractures yielded 7.1% of IOIP compared to the case of one fracture and two fractures which produced 11.9% and 17.6% of OIP, respectively. Furthermore, in the no-fracture, one-fracture, and two-fracture cores, more EOR oil was produced by increasing the CO2fraction in the injection gas mixture. This research provides a basis for interpreting core flooding oil recovery results under expansion drive and gas injection EOR—both in presence and absence of interconnected micro- and macro-fractures in the flow path. Finally, the CO2 injection results quantify the CCUS efficacy in regard to the amount of sequestered CO2 from pore trapping in the early reservoir life. For the long-term CO2 trapping, one needs to include the chemical interaction of CO2 with the formation brine and rock matrix.
In the Wattenberg Field, the Reservoir Characterization Project at the Colorado School of Mines and Occidental Petroleum Corporation (Oxy) (formerly the Anadarko Petroleum Corporation) collected time-lapse seismic data for characterization of changes in the reservoir caused by hydraulic fracturing and production in the Niobrara Formation and Codell Sandstone member of the Carlile Formation. We have acquired three multicomponent seismic surveys to understand the dynamic reservoir changes caused by hydraulic fracturing and production of 11 horizontal wells within a 1 mi2 section (the Wishbone Section). The time-lapse seismic survey acquisition occurred immediately after the wells were drilled, another survey after stimulation, and a third survey after two years of production. In addition, we integrate core, petrophysical properties, fault and fracture characteristics, as well as P-wave seismic data to illustrate reservoir properties prior to simulation and production. Core analysis indicates extensive amounts of bioturbation in zones of high total organic content (TOC). Petrophysical analysis of logs and core samples indicates that chalk intervals have high amounts of TOC (>2%) and the lowest amount of clay in the reservoir interval. Core petrophysical characterization included X-ray diffraction analysis, mercury intrusion capillary pressure, N2 gas adsorption, and field emission scanning electron microscopy. Reservoir fractures follow four regional orientations, and chalk facies contain higher fracture density than marl facies. Integration of these data assist in enhanced well targeting and reservoir simulation.
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