Introducing amorphous and ultrathin nanosheets of transition bimetal phosphate arrays that are highly active in the oxygen evolution reaction (OER) as shells over an electronically modulated crystalline core with low hydrogen absorption energy for an excellent hydrogen evolution reaction (HER) can boost the sluggish kinetics of the OER and HER in alkaline electrolytes. Therefore, in this study, ultrathin and amorphous cobalt‐nickel‐phosphate (CoNiPO
x
) nanosheet arrays are deposited over vanadium (V)‐doped cobalt‐nitride (V
3%
‐Co
4
N) crystalline core nanowires to obtain amorphous‐shell@crystalline‐core mesoporous 3D‐heterostructures (CoNiPO
x
@V‐Co
4
N/NF) as bifunctional electrocatalysts. The optimized electrocatalyst shows extremely low HER and OER overpotentials of 53 and 270 mV at 10 mA cm
−2
, respectively. The CoNiPO
x
@V
3%
‐Co
4
N/NF (+/−) electrolyzer utilizing the electrocatalyst as both anode and cathode demonstrates remarkable overall water‐splitting activity, requiring a cell potential of only 1.52 V at 10 mA cm
−2
, 30 mV lower than that of the RuO
2
/NF (+)/20%‐Pt/C/NF (−) electrolyzer. Such impressive bifunctional activities can be attributed to abundant active sites, adjusted electronic structure, lower charge‐transfer resistance, enhanced electrochemically active surface area (ECSA), and surface‐ and volume‐confined electrocatalysis resulting from the synergistic effects of the crystalline V
3%
‐Co
4
N core and amorphous CoNiPO
x
shells boosting water splitting in alkaline media.
Density functional theory simulations demonstrate that single and triple Ta-atom catalysts anchored to C2N monolayer act as superior catalysts for the nitrogen reduction reaction via alternating and distal pathways.
A boron anchored defective Mo2C monolayer with superior electrocatalytic activity for the NRR at 0.41 eV along the distal pathway on account of a more positive B p-band center.
The
position of the anchoring group is systematically changed with
a series of alkyl group wrapped donor–acceptor–donor
(D–A–D) based squaraine dyes, 4-SQ to 7-SQ, for the
use in dye-sensitized solar cells (DSSCs). By this approach, the orientation
as well as the self-assembly of the sensitizers can be controlled
on the semiconducting TiO2 surface. All of the dyes functionalized
with hydrophobic alkyl groups at sp3-C and N atoms of the
indoline units that is far away from
the TiO2 surface to control the self-assembly of dyes and
passivate the surface. Controlling both the orientation as well as
the self-assembly of the sensitizers synergistically enhances the V
oc of the DSSC device by imparting the dipole
moment on the TiO2 surface and minimizing the interfacial
charge recombination process of electrons from TiO2 to
the oxidized electrolyte, respectively. Further, the presence of a meta-carboxyl group with respect to the N atom of the indoline
donor unit for the dyes 4-SQ and 6-SQ makes them nonconductive for
the charge injection process, which sheds light on the importance
of through-space electron transfer for the device performance. Emission
from the relaxed twisted state was found to be a deactivation pathway
for 4-SQ on TiO2 and ZrO2, which revealed the
importance of structural factors that promote spatial interaction
between the sensitizer and metal oxide surface. Computational studies
showed the systematic changes in the dipole moment for the sensitizers
4-SQ, 5-SQ, and 6-SQ upon anchoring to the TiO2 surface.
The DSSC device performance varied with the position of anchoring
groups in the sensitizers. The DSSC device performance of 5-SQ indicates
a J
sc value of 11.35 mA cm–2, V
oc of 0.698 V, and
ff of 77% corresponding to a power conversion efficiency of 6.08%
in the presence of 3 equiv of coadsorbent CDCA, which is nearly 1.5
times higher than 6-SQ (V
oc 0.7 V, J
sc 7.76 mA cm–2, ff
76%, and η 4.14%) and 2.6 times higher than 4-SQ (V
oc 0.658 V, J
sc 4.42 mA cm–2, ff 78%, and η 2.28%). IPCE studies revealed
the importance of orientation for the charge injection and self-assembly
of dyes, as devices with 5-SQ and 6-SQ as a sensitizer showed 94 and
77% response at 578 nm, respectively, which correspond to the aggregated
structure of the dye. Mott–Schottky and IPCE experiments showed
that the orientation of sensitizers could modulate the V
oc due to the shift in the flat band potential of TiO2.
Catalysis on two-dimensional (2D) substrates with metal clusters or centers is generally dealt with as a surface phenomenon under the conjecture that the delocalized electron density is the driving force. When single atom catalysts (SACs) are anchored on such materials with delocalized electron density, for instance graphene, the stimulant for catalysis may be either the d-electrons on the metal or the system altogether. To understand the contributing factors of catalysis on such systems, a case study of dinitrogen (N 2 ) activation on Mo anchored graphene has been made by employing periodic and finite models of graphene. The periodic model represents a continuum of SACs anchored periodically on graphene, while the finite models are graphene nanoflakes of varying sizes and edge orientations. In addition to the physical aspects, such as size/finiteness of graphene, the influence of varying chemical compositions of the substrate on the activity is also evaluated by doping graphene with different B and N concentrations. This study, while clearly bringing out the connotation of regulating atomic composition of graphene substrate for dinitrogen activation, also surprisingly unveils the relative insignificance of varying the size and edge effects of the substrate. These features are highlighted through an analysis of red shift in the N−N stretching frequency, charge transfer to dinitrogen from the catalytic system, and structural and electronic characteristics of the catalytic system. The total and projected density of states plots reveal hybridization between the metal d orbitals and the p orbitals of carbon and nitrogen in the valence band. On the other hand, the frontier molecular orbital analysis also depicts a strong chemisorption of dinitrogen with the metal−graphene supports on account of direct hybridization between the d orbitals of the supported metal atom and the p orbitals of dinitrogen. The Bader and Loẅdin charge distribution on the adsorbed dinitrogen in periodic and finite models shows the preeminence of local site over the surface activity.
Heteroatom‐doped transition metal‐oxides of high oxygen evolution reaction (OER) activities interfaced with metals of low hydrogen adsorption energy barrier for efficient hydrogen evolution reaction (HER) when uniformly embedded in a conductive nitrogen‐doped carbon (NC) matrix, can mitigate the low‐conductivity and high‐agglomeration of metal‐nanoparticles in carbon matrix and enhances their bifunctional activities. Thus, a 3D mesoporous heterostructure of boron (B)‐doped cobalt‐oxide/cobalt‐metal nanohybrids embedded in NC and grown on a Ni foam substrate (B‐CoO/Co@NC/NF) is developed as a binder‐free bifunctional electrocatalyst for alkaline water‐splitting via a post‐synthetic modification of the metal–organic framework and subsequent annealing in different Ar/H2 gas ratios. B‐CoO/Co@NC/NF prepared using 10% H2 gas (B‐CoO/Co@NC/NF [10% H2]) shows the lowest HER overpotential (196 mV) and B‐CoO/Co@NC/NF (Ar), developed in Ar, shows an OER overpotential of 307 mV at 10 mA cm−2 with excellent long‐term durability for 100 h. The best anode and cathode electrocatalyst‐based electrolyzer (B‐CoO/Co@NC/NF (Ar)(+)//B‐CoO/Co@NC/NF (10% H2)(−)) generates a current density of 10 mA cm−2 with only 1.62 V with long‐term stability. Further, density functional theory investigations demonstrate the effect of B‐doping on electronic structure and reaction mechanism of the electrocatalysts for optimal interaction with reaction intermediates for efficient alkaline water‐splitting which corroborates the experimental results.
It is highly imaginary that the outcome of a combination of two complementary resources leads to answer an alarming global issue. One such possible example is the solar seawater splitting for ‘clean fuel’ H2 generation. Since the catalytic activity and stability of the photocatalysts are substantially challenged in seawater, the design of an efficient and stable photocatalyst is highly desirable. Herein, we demonstrate the solar seawater splitting by a two‐dimensional polymer catalyst derived from metalloporphyrin bearing multi‐hydroxyl groups. A bimetallic (Co and Ni) porphyrin 2D‐polymer exhibits excellent long‐term durability of 15 cycles of H2 and O2 generation in 200 days from pure water without a considerable decrease in efficiency. Detailed studies using river and seawaters also show the reliable performance of the catalyst over repeated cycles. Here the deactivation modes of catalytic activity have been nullified by the layered metalloporphyrin polymer structure through stable π−π stacking, signifying the molecular design of 2D‐polymer photocatalyst.
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