Teff straw, a by-product of Teff, mainly available in Ethiopia, has not been studied much for biosorbent production. The present study has investigated the effects of modification and optimization of process parameters (viz., concentration of modifying agent (H3PO4 and KOH), modifying temperature, and modifying time) on the Cr (VI) removal efficiency of using chemically activated Teff straw biosorbent by RSM followed by BBD. The maximum Cr (VI) removal was obtained using an H3PO4-modified Teff straw biosorbent of 92.5% with 2 M concentration of the modifying agent, 110°C, and 4 h. Similarly, maximum Cr (VI) removal using KOH-modified Teff straw biosorbent of 95.2% was obtained with 1.5 M activating agent concentration, 105°C activation temperature, and 3.5 h activation time. In addition, the effects of adsorption parameters (viz., biosorbent dosage, temperature, initial concentration of Cr (VI), and contact time) were investigated. The maximum removal efficiency was attained at 2 g of biosorbent dosage, 4 h contact, 75 mg/L of initial Cr (VI) concentration, and 25°C sorption temperature. In addition, isotherm, kinetic, and thermodynamic studies for Cr (VI) biosorption were studied. The experimental adsorption data were well fitted with the Langmuir isotherm and pseudo-second-order kinetic model with higher correlation coefficient in both untreated and chemically modified Teff straw biosorbent. The investigated thermodynamic parameters ( Δ H o , Δ S o , and Δ G o ) confirmed that Cr (VI) metal ions’ adsorption process onto Teff straw biosorbent was spontaneous and endothermic.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
334 Leonard St
Brooklyn, NY 11211
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.