The physico-chemical characteristics of particulate matter (PM) in African cities remain poorly known due to scarcity of observation networks. Magnetic parameters of PM are robust proxies for the emissions of Fe-bearing particles. This study reports the first magnetic investigation of PM2.5 (PM with aerodynamic size below 2.5 m) in Africa performed on weekly PM2.5 filters collected in Abidjan (Ivory Coast) and Cotonou (Benin) between 2015 and 2017. The magnetic mineralogy is dominated by magnetite-like low coercivity minerals. Mass normalized SIRM are 1.65e−2A□m/kg and 2.28e−2A□m/kg for Abidjan and Cotonou respectively. Hard coercivity material (S-ratio = 0.96 and MDF = 33 mT) is observed during the dry dusty season. Wood burning emits less iron oxides by PM2.5 mass when compared to traffic sources. PM2.5 magnetic granulometry has a narrow range regardless of the site or season. The excellent correlation between the site-averaged element carbon concentrations and SIRM suggests that PM2.5 magnetic parameters are linked to primary particulate emission from combustion sources.

Ultrafine grains of magnetic minerals provide reliable recordings of both naturally occurring and anthropogenically generated particulate matter in polluted air; magnetic data can be used to understand biogenic iron-cycling in anaerobic environments, as well as pedogenesis and palaeoclimate studies of loess soils. The ultrafine fraction is produced under specific conditions and can be easily recognized by its superparamagnetic (SP) behaviour. Many proxies have been proposed to account for the SP contribution by measuring its susceptibility dependency with frequency (frequency effect) or the magnetization loss after removing an external inducing field. Here we introduce the Superparamagnetic Concentration and Dipole Moment (SPCDM) procedure for quantitative interpretation of SP magnetization. This procedure is well suited to SP carriers with a fast magnetization decay (<1 s), as would be expected for magnetic minerals with a grain size distribution lying below the blocking volume for stable, single-domain (SD) magnetization. SPCDM requires a dedicated experimental procedure to isolate the SP response from the paramagnetic and remnant effects, as observed in samples with mixed contributions. The proposed technique was tested using synthetic, nanoparticles of magnetite and then to characterize the magnetic properties of air particulate matter (PM) sampled at Jânio Quadros tunnel in São Paulo, Brazil. For nano-sized magnetite, SPCDM estimates for dipole moment are invariable with mass concentration and consistent with the published results; estimates for particle concentration are strongly correlated with true mass concentration (R 2 = 0.96). For air PM, SPCDM estimates a particle size with a diameter of 7.7 ± 0.1 nm, a kind of ultrafine magnetic material not previously recognized in air pollutants.

No abstract

No abstract

In this work we present results of the magnetic properties characterization of sediment samples from a brownfield site that is generating methane biogas in São Paulo–Brazil. We applied interpretation procedures (frequency dependent susceptibility and time-dependent Isothermal Remanent Magnetization) appropriate to study the ultrafine magnetic fraction response of the samples. The higher content of superparamagnetic (SP) particles correlates well with the detected biogas pockets, suggesting that the methanogens activity produces these ultrafine particles, different from the magnetic particles at other depth levels. We propose the use of two simple measurement and interpretation techniques to identify such magnetic particles fingerprints. The results presented here support the use of environmental magnetism techniques to investigate biogeochemical processes of anaerobic microbial activity.

Children's exposure to air pollution affects both their health and learning skills. Fine and ultrafine particulate matter (PM2.5, PM1), notably issued from traffic sources in urban centers, belong to the most potential harmful health hazards. However their monitoring and the society's awareness on their dangers need to be consolidated. In this study, raising teacher and pupil involvement for air quality improvement in their schools environment is reached through developing a passive monitoring technique (bio‐sensors made of tree bark). The experiment was implemented in two urban elementary schools situated close to a main traffic road of the city of Toulouse (South of France). Magnetic properties, carbonaceous fraction measurements, and scanning electronic microscopy (SEM‐EDX) investigations were realized both on passive bio‐sensors and filters issued from active sampling. We find that traffic is the main PM1 source for both outdoors and indoors at schools. Higher levels of outdoor PM in the school's environments compared to urban background are reached especially in the cold period. The schools proximity to a main traffic source and lack of ventilation are the main causes for observed PM1 accumulation in classrooms. The co‐working experiment with educational teams and pupils shows that the use of bio‐sensors is a driver for children empowerment to air pollution and therefore represents a potential key tool for the teachers though limiting eco‐anxiety. As PM accumulation is observed in many scholar environments across Europe, the proposed methodology is a step toward a better assessment of PM impact on pupil's health and learning skills.

No abstract