Nanophotonics based on resonant nanostructures and metasurfaces made of halide perovskites have become a prospective direction for efficient light manipulation at the subwavelength scale in advanced photonic designs. One of the main challenges in this field is the lack of large‐scale low‐cost technique for subwavelength perovskite structures fabrication preserving highly efficient luminescence. Here, unique properties of halide perovskites addressed to their extremely low thermal conductivity (lower than that of silica glass) and high defect tolerance to apply projection femtosecond laser lithography for nanofabrication with precise spatial control in all three dimensions preserving the material luminescence efficiency are employed. Namely, with CH3NH3PbI3 perovskite highly ordered nanoholes and nanostripes of width as small as 250 nm, metasurfaces with periods less than 400 nm, and nanowire lasers as thin as 500 nm, corresponding to the state‐of‐the‐art in multistage expensive lithographical methods are created. Remarkable performance of the developed approach allows to demonstrate a number of advanced optical applications, including morphology‐controlled photoluminescence yield, structural coloring, optical‐ information encryption, and lasing.
We have developed a novel nanophotonic design representing a plasmonic hybrid Au–Si nanosponge structure. The obtained results provide an understanding of the internal structure and physics of this hybrid nanosponge.
Counterfeiting is a severe problem of world economics and trade when non-authorized manufacturers produce and distribute various goods as products of famous brands. Many economic spheres from daily consumer goods and pharmaceuticals
We suggest a new strategy for creating stimuliresponsive bio-integrated optical nanostructures based on Mieresonant silicon nanoparticles covered by an ensemble of similarity negatively charged polyelectrolytes (heparin and sodium polystyrene sulfonate). The dynamic tuning of the nanostructures optical response is due to light-induced heating of the nanoparticles and swelling of the polyelectrolyte shell. The resulting hydrophilic/hydrophobic transitions significantly change the shell thickness and reversible shift of the scattering spectra for individual nanoparticles up to 60 nm. Our findings bring novel opportunities for the application of smart nanomaterials in nanomedicine and bio-integrated nanophotonics.
Luminescent security labels are effective platforms for protection of consumer goods from counterfeiting. However, the lifetimes of such security approaches are limited due to narrow-band photoluminescent features of the label elements, which can be used for the protection technology disclosure. In this paper, a novel concept for the application of non-linear white-light luminescence from hybrid metal-semiconductor structures fabricated by direct femtosecond laser writing for the creation of physically unclonable security labels is proposed. A close connection is demonstrated between the internal composition of hybrid structures, which is controlled at the fabrication stage, and their non-linear optical signals. It is shown that the application of decorrelation procedure based on discrete cosine transform and polar codes for label coding can overcome the problem of the white-light photoluminescent spectra correlation. The proposed fabrication approach and coding strategy allows reaching a high degree of device uniqueness (up to 99%), bit uniformity (close to 0.5), and encoding capacity up to 1.25 × 10 437 in a single label element. The results demonstrate that the barriers for the application of white-light luminescent nano-objects for the creation of physically unclonable labels are removed.
A micro- or nanosized electrically controlled source of optical radiation is one of the key elements in optoelectronic systems. The phenomenon of light emission via inelastic tunneling (LEIT) of electrons through potential barriers or junctions opens up new possibilities for development of such sources. In this work, we present a simple approach for fabrication of nanoscale electrically driven light sources based on LEIT. We employ STM lithography to locally modify the surface of a Si/Au film stack via heating, which is enabled by a high-density tunnel current. Using the proposed technique, hybrid Si/Au nanoantennas with a minimum diameter of 60 nm were formed. Studying both electronic and optical properties of the obtained nanoantennas, we confirm that the resulting structures can efficiently emit photons in the visible range because of inelastic scattering of electrons. The proposed approach allows for fabrication of nanosized hybrid nanoantennas and studying their properties using STM.
It is very natural to use silicon as a primary material for microelectronics. However, silicon application in nanophotonics is limited due to the indirect gap of its energy band structure. To improve the silicon emission properties, it can be combined with a plasmonic part. The resulting metal–dielectric (hybrid) nanostructures have shown their excellence compared to simple metallic dielectric nanostructures. Still, in many cases, the fabrication of such structures is time consuming and quite difficult. Here, for the first time, we demonstrate a single-step and lithography-free laser-induced dewetting of bi-layer nanoscale-thickness gold–silicon films supported by a glass substrate to produce hybrid nanoparticles. For obtaining hybrid nanoparticles, we study nonlinear photoluminescence by mapping their optical response and morphology by scanning electron microscopy. This method can be used for the fabrication of arrays of hybrid nanoparticles providing white-light photoluminescence with a good control of their microscopic sizes and position. The developed approach can be useful for a wide range of photonic applications including the all-optical data processing and storage where miniaturization down to micro- and nanoscale together with an efficiency increase is of high demand.
Plasmon sponge nanostructures have occupied a special role in the field of plasmonics and nanophotonics: sensors and advanced source of white emission. If the pores of a golden spongy nanostructure are filled with silicon, the result will be a promising source of broadband radiation with high efficiency due to the localization of the field by a structure with a high surface-to-volume ratio. This paper presents the results of photoluminescence generation with multiphoton absorption and second-harmonic generation obtained from hybrid sponge Si/Au nanoparticles. The particles have been fabricated by femtosecond laser ablation at room temperature in the air. Experiments have shown the ability to generate broadband photoluminescence in the range of 500 – 800 nm (0.93 eV). The obtained results can be applied for creation of white light luminescent metasurfaces and advanced nanophotonic spectroscopy devices.
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