The reaction of Ca derived from silicate weathering with CO 2 in the world's oceans to form carbonate minerals is a critical step in long-term climate moderation. Ca is delivered to the oceans primarily via rivers, where it is transported either as dissolved species or within suspended material. The relative importance for climate moderation of riverine dissolved Ca vs. suspended Ca transport stems from the total Ca flux and its climate dependence. Data in the literature suggest that, within uncertainty, global riverine dissolved Ca flux is equal to suspended material Ca flux. To determine how these fluxes depend on temperature and rainfall, a 40 yr field study was performed on 4 catchments in northeastern Iceland: Jökulsá á Fjöllum at Grímsstadir, Jökulsá á Dal at Brú, Jökulsá á Dal at Hjardarhagi, and Jökulsá í Fljótsdal at Hóll. Suspended material Ca flux depends more on seasonal and annual temperatures and rainfall variation than does dissolved Ca flux in all four catchments. For example, the average difference between the annual maximum and minimum daily suspended Ca flux for the Jökulsá á Dal at Brú is four orders of magnitude, whereas the difference for dissolved Ca flux is only approximately one order of magnitude. Similarly, the annual dissolved Ca flux for this river varies by a factor of 2.6, whereas its annual suspended Ca flux varies by a factor of 7.1. Because suspended material Ca flux is more dependent on climate, it provides a stronger negative feedback for stabilizing Earth's temperature through the greenhouse effect.
Abstract. The three-dimensional flow, temperature and salinity fields of the North Atlantic, including the Arctic Ocean, covering the time period 1992 to 2006 are simulated with the numerical ocean model CODE. The simulation reveals several new insights and previously unknown structures which help us to clarify open questions on the regional oceanography of Icelandic waters. These relate to the structure and geographical distribution of the coastal current, the primary forcing of the North Icelandic Irminger Current (NIIC) and the path of the Atlantic Water south-east of Iceland. The model's adaptively refined computational mesh has a maximum resolution of 1 km horizontal and 2.5 m vertical in Icelandic waters. CTD profiles from this region and the river discharge of 46 Icelandic watersheds, computed by the hydrological model WaSiM, are assimilated into the simulation. The model realistically reproduces the established elements of the circulation around Iceland. However, analysis of the simulated mean flow field also provides further insights. It suggests a distinct freshwater-induced coastal current that only exists along the south-west and west coasts, which is accompanied by a counter-directed undercurrent. The simulated transport of Atlantic Water over the Icelandic shelf takes place in a symmetrical system of two currents, with the established NIIC over the north-western and northern shelf, and a hitherto unnamed current over the southern and southeastern shelf, which is simulated to be an upstream precursor of the Faroe Current (FC). Both currents are driven by barotropic pressure gradients induced by a sea level slope across the Greenland-Scotland Ridge. The recently discovered North Icelandic Jet (NIJ) also features in the model predictions and is found to be forced by the baroclinic pressure field of the Arctic Front, to originate east of the Kolbeinsey Ridge and to have a volume transport of around 1.5 Sv within northern Denmark Strait. The simulated multi-annual mean Atlantic Water transport of the NIIC increased by 85 % during 1992 to 2006, whereas the corresponding NIJ transport decreased by 27 %. Based on our model results we propose a new and further differentiated circulation scheme of Icelandic waters whose details may inspire future observational oceanography studies.
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