Covalent organic frameworks (COFs), in which molecular building blocks form robust microporous networks, are usually synthesized as insoluble and unprocessable powders. We have grown two-dimensional (2D) COF films on single-layer graphene (SLG) under operationally simple solvothermal conditions. The layered films stack normal to the SLG surface and show improved crystallinity compared with COF powders. We used SLG surfaces supported on copper, silicon carbide, and transparent fused silica (SiO(2)) substrates, enabling optical spectroscopy of COFs in transmission mode. Three chemically distinct COF films grown on SLG exhibit similar vertical alignment and long-range order, and two of these are of interest for organic electronic devices for which thin-film formation is a prerequisite for characterizing their optoelectronic properties.

Inherent properties of graphene can be experienced by integrating it with different nanomaterials to form unique composite materials. Decorating the surface of graphene sheets with nanoparticles (NPs) is one of the recent approaches taken up by scientists all over the world. This article describes a simple synthesis route to preparing stable Ni NP-reduced graphene oxide (Ni-RGO) composite material. The otherwise unstable bare Ni NPs are stabilized when embedded in the RGO sheets. This synthesized composite material has a potential application in the formic acid-induced reduction of highly toxic aqueous Cr(VI) at room temperature (25 °C). The reduction of dichromate using formic acid as a reducing agent is a well-known redox reaction. However, the rate of the reaction is very slow at room temperature, which can be enhanced very significantly in the presence of Ni-RGO by introducing an intermediate redox step with formic acid. The Ni-RGO composite material is an easy to prepare, cheap, stable, reusable material that has the potential to replace costly Pd NPs used in this context. Ni-RGO is also found to be very active in enhancing the rate of reduction of other metal ions in the presence of formic acid at room temperature.

A novel approach for bulk synthesis of lithium-intercalated graphene sheets through the reduction of exfoliated graphene oxide in liquid ammonia and lithium metal is reported. It is demonstrated here that as-synthesized lithiated graphite oxide sheets (Li-RGO) can be directly used as an electrode material in lithium batteries. The electrochemical studies on Li-RGO electrodes show a significant enhancement in the specific capacity of the lithium battery over commercially available graphite electrodes. Partial intercalation of lithium ions in between graphene layers makes this material a good candidate for electrochemical energy storage applications.

Synthesis of Cu2O-amine-functionalized graphite nanosheet (AFGNS) composite has been accomplished at room temperature. In the first step, AFGNS is synthesized by wet chemical functionalization where the -NH2 groups formed on nanosheet surface help to anchor the Cu(2+) ions homogeneously through coordinate bonds. Reduction of Cu(2+) (3.4 × 10(-2) mmol) in the presence of NaBH4 (1.8 mmol) can be restricted to Cu(1+) on AFGNS surface at room temperature. This leads to the formation of uniform Cu2O nanoparticles (NP) on AFGNS. The role played by the -NH2 groups in anchoring Cu(2+) ions and followed by stabilizing the Cu2O NP on AFGNS was understood by controlled reactions in the absence of -NH2 groups and without any graphitic support, respectively. The prepared Cu2O-AFGNS composite shows excellent catalytic activity toward degradation of an azo dye, methyl orange, which is an environmental pollutant. The dye degradation proceeds with high rate constant value, and the composite shows high stability and excellent reuse capability.

Dispersions of carbon nanotube salts prepared by treating single-walled carbon nanotubes (SWNTs) with lithium in liquid ammonia react with aryl and alkyl sulfides by single electron transfer (SET) to yield transient radical anions that dissociate into carbon-centered free radicals and mercaptide. The free radicals add to the sidewalls of the nanotubes or recombine with SWNT radical anions. AFM images indicate that the derivatized SWNTs are partially debundled. Disulfides react with carbon nanotube salts to yield SWNTs functionalized by sulfur-centered radicals.

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Oxidation of graphite may be carried out by reaction with meta-chloroperoxybenzoic acid to yield graphite epoxide. Scanning tunneling microscopy (STM) showed that the functionalization occurs at the edges rather than on the basal plane of the graphite. Quantification of the epoxide content is possible through the deepoxidation reaction using MeReO3/PPh3.

Carbon nanotube salts, prepared by treating single-walled carbon nanotubes (SWNTs) with lithium in liquid ammonia, react with N-halosuccinimide by electron transfer to generate transient radical anions that yield succinimidyl radicals and halide anions. Similarly, alkyl peroxides, when treated with SWNT salts, give rise to alkoxy radicals and alkoxides. The free radicals add to the sidewalls of nanotube salts to form succinimidyl and alkoxy derivatized SWNTs. The functionalized SWNTs can then be converted to amino and hydroxyl SWNTs by hydrolysis with hydrazine or with fuming sulfuric acid, respectively. Hydrolysis of alkoxy derivatized SWNTs with D 2 O/D 2 SO 4 led to the deuterated analogue of hydroxy SWNT, as shown by Fourier transform infrared (FTIR) spectroscopy. These reactions constitute a twostep synthesis of aminated and hydroxylated SWNTs. Covalent sidewall functionalization was confirmed by thermal gravimetric analysis (TGA), Raman spectroscopy, FTIR spectroscopy, and high-resolution transmission electron microscopy (HRTEM). Aminated and hydroxylated SWNTs were characterized by FTIR and X-ray photoelectron spectroscopy (XPS).