Moiréheterobilayers host interlayer excitons in a natural, periodic array of trapping potentials. Recent work has elucidated the structure of the trapped interlayer excitons and the nature of photoluminescence (PL) from trapped and itinerant charged complexes such as interlayer trions in these structures. In this paper, our results serve to add to the understanding of the nature of PL emission and explain its characteristic blueshift with increasing carrier density, along with demonstrating a significant difference between the interlayer exciton-trion conversion efficiency as compared to both localized and itinerant intralayer species in conventional monolayers. Our results show the absence of optical generation of trions in these materials, which we suggest arises from the highly localized, near subnanometer confinement of trapped species in these Moirépotentials.
Electron-hole liquids(EHLs), a correlated state of matter and a thermodynamic liquid, have recently been found to exist at room temperature in suspended monolayers of MoS 2 . Appreciably higher rates of radiative recombination inside the liquid as compared to free excitons hold promise for optoelectronic applications such as broadband lasing. In this paper, we show that leveraging the valley physics in MoS 2 may be a route towards achieving tunability of specific characteristics of an EHL, such as emission wavelength, linewidth, and most importantly, the liquid density. The conditions under which EHLs form, in bulk semiconductors as well as TMDC monolayers are quite stringent, requiring high crystal purity and cryogenic temperatures in bulk semiconductors, and suspension in monolayers. Using a simple yet powerful model for describing free excitons and show that a phase transition into the EHL state may be feasible in substrate-supported monolayer samples. More repeatable experimental realizations of EHLs may be essential to answer questions regarding the nature of electron-hole correlations and how they may be used to generate non-trivial states of light.
Moiré heterobilayers host interlayer excitons in a natural, periodic array of trapping potentials. Recent work has elucidated the structure of the trapped interlayer excitons and the nature of photoluminescence (PL) from trapped and itinerant charged complexes such as interlayer trions in these structures. In this paper, our results serve to add to the understanding of the nature of PL emission and explain its characteristic blueshift with increasing carrier density, along with demonstrating a significant difference between the interlayer exciton-trion conversion efficiency as compared to both localized and itinerant intra-layer species in conventional monolayers. Our results show the absence of optical generation of trions in these materials, which we suggest arises from the highly localized, near sub-nm confinement of trapped species in these Moiré potentials.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.