An important stage in an analysis of a multibody system (MBS) with elastic elements by the finite element method is the assembly of the equations of motion for the whole system. This assembly, which seems like an empirical process as it is applied and described, is in fact the result of applying variational formulations to the whole considered system, putting together all the finite elements used in modeling and introducing constraints between the elements, which are, in general, nonholonomic. In the paper, we apply the method of Maggi's equations to realize the assembly of the equations of motion for a planar mechanical systems using finite two-dimensional elements. This presents some advantages in the case of mechanical systems with nonholonomic liaisons.
This paper proposes a new method for calculating the monomer reactivity ratios for binary copolymerization based on the terminal model. The original optimization method involves a numerical integration algorithm and an optimization algorithm based on k-nearest neighbour non-parametric regression. The calculation method has been tested on simulated and experimental data sets, at low (<10%), medium (10–35%) and high conversions (>40%), yielding reactivity ratios in a good agreement with the usual methods such as intersection, Fineman–Ross, reverse Fineman–Ross, Kelen–Tüdös, extended Kelen–Tüdös and the error in variable method. The experimental data sets used in this comparative analysis are copolymerization of 2-(N-phthalimido) ethyl acrylate with 1-vinyl-2-pyrolidone for low conversion, copolymerization of isoprene with glycidyl methacrylate for medium conversion and copolymerization of N-isopropylacrylamide with N,N-dimethylacrylamide for high conversion. Also, the possibility to estimate experimental errors from a single experimental data set formed by n experimental data is shown.
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