We formulate the scaled particle theory for a general mixture of hard isosceles triangles and calculate different phase diagrams for the one-component fluid and for certain binary mixtures. The fluid of hard triangles exhibits a complex phase behavior: (i) the presence of a triatic phase with sixfold symmetry, (ii) the isotropic-uniaxial nematic transition is of first order for certain ranges of aspect ratios, and (iii) the one-component system exhibits nematic-nematic transitions ending in critical points. We found the triatic phase to be stable not only for equilateral triangles but also for triangles of similar aspect ratios. We focus the study of binary mixtures on the case of symmetric mixtures: equal particle areas with aspect ratios (κ_{i}) symmetric with respect to the equilateral one, κ_{1}κ_{2}=3. For these mixtures we found, aside from first-order isotropic-nematic and nematic-nematic transitions (the latter ending in a critical point): (i) a region of triatic phase stability even for mixtures made of particles that do not form this phase at the one-component limit, and (ii) the presence of a Landau point at which two triatic-nematic first-order transitions and a nematic-nematic demixing transition coalesce. This phase behavior is analogous to that of a symmetric three-dimensional mixture of rods and plates.

Liquid-crystalline ordering in vertically vibrated granular monolayers of metallic rods confined in annuli of different sizes is examined. The annuli consist of circular cavities with a central circular obstruction. In the absence of the central obstruction, rods of low aspect ratio exhibit global tetratic order, except for the existence of four small defected regions which restore the tetratic symmetry broken by the circular confinement. However, very different configurations are observed in the annuli, with a complex structure consisting of alternating layered regions separated by tetratic domain walls. We use concepts of equilibrium elastic theory for liquid crystals and topology along with arguments based on dissipation mechanisms to qualitatively explain this behavior. The results show that selective confinement of vertically vibrated monolayers of rods could be used as a tool to study the creation and dynamics of various types of defects in ordered systems.

We use the density-functional formalism, in particular the scaled-particle theory, applied to a length-polydisperse hard-rectangle fluid to study its phase behavior as a function of the mean particle aspect ratio κ_{0} and polydispersity Δ_{0}. The numerical solutions of the coexistence equations are calculated by transforming the original problem with infinite degrees of freedoms to a finite set of equations for the amplitudes of the Fourier expansion of the moments of the density profiles. We divide the study into two parts. The first one is devoted to the calculation of the phase diagrams in the packing fraction η_{0}-κ_{0} plane for a fixed Δ_{0} and selecting parent distribution functions with exponential (the Schulz distribution) or Gaussian decays. In the second part we study the phase behavior in the η_{0}-Δ_{0} plane for fixed κ_{0} while Δ_{0} is changed. We characterize in detail the orientational ordering of particles and the fractionation of different species between the coexisting phases. Also we study the character (second vs first order) of the isotropic-nematic phase transition as a function of polydispersity. We particularly focus on the stability of the tetratic phase as a function of κ_{0} and Δ_{0}. The isotropic-nematic transition becomes strongly of first order when polydispersity is increased: The coexistence gap widens and the location of the tricritical point moves to higher values of κ_{0} while the tetratic phase is slightly destabilized with respect to the nematic one. The results obtained here can be tested in experiments on shaken monolayers of granular rods.