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Nanotechnology has facilitated unique ways of developing novel nano-composites. In that sense, polymer-based nano-composites are being extensively researched for their outstanding properties as a result of incorporating nano-fillers in the polymer matrix. They have activated enormous research interests owing to their potential in addressing environmental issues, packaging, optics, electronics, battery electrolytes, pneumatic actuation, molecular separations, sensors, biomedical applications, etc. Hence, the authors intend to consolidate reported information about these polymer matrices, diverse inorganic nanofillers, and nano-filled polymer composites for improvement in properties and future advanced applications. The review exhaustively covers 15 years of literature on theoretical, experimental, and application aspects of PVA & PMMA-based nano-composites. It also summarizes the structure-property correlations that govern their performance. Hence this review is hoped to provide the readers with stimulating insights on strategies, noteworthy challenges, and future opportunities/prospects in developing polymer nano-composites that may cater to the need of our society and scientific industries as well.
This study was an attempt to combine fused deposition modelling and hot press moulding technique to fabricate hybrid polymer composites using acrylonitrile butadiene styrene (ABS) polymer, woven glass fibre (GF) and woven carbon fibre (CF). The composite specimens were subjected towere subjected to mechanical and thermal characterization.Tensile strength of GF/ABS and GF/CF/ABS composite were far higher than the virgin ABS. GF/ABS composites displayedimproved thermal resistance by giving a final residue of 42.36%, followed by GF/CF/ABS hybrid composites as per the thermogravimetric analysis. Thermomechanical analysis revealed the coefficient of thermal expansion in the order: ABS > GF/ABS > GF/CF/ABS. The entropy obtained from the DSC curve was of higher value for composites than the ABS. The ABS based composites fabricated from this technique can be applicable to structural parts in the automobiles, aircrafts, shipping vessels, etc.
Silver/Zinc Oxide nanocomposites (Ag-ZnO NCs) were fabricated by varying the weight percentages of both Ag and ZnO for investigating its photocatalytic activity. The structural, morphology and optical response of the prepared nanocomposites were examined with PXRD, FESEM, TEM, EDAX, FT-IR, UV-Vis-DRS and PL spectroscopy. The effect of Ag and ZnO concentrations on these nanocomposites was examinedby analyzing thephotocatalytic activity towards Methylene Blue (MB) dye degradationunder the UV irradiation. The overall results suggested that, AZ1:1 NC achieved better photocatalytic activity than AZ1:2 and AZ2:1 composition. Therefore, the present study demonstrated the viability of the Ag-ZnO NCs in remediation of environmental pollutant and treatment of waste water.
In this present work, a review of fatigue strength on bio‐nano composites was presented. Generally, the biocomposites possessed higher fatigue strength than the conventional materials. Because the propagation in biocomposites can be arrested due to their internal structure, whereas the damages occur in the matrix and/or at the fiber/matrix interface region. In the case of conventional materials, the cracks would rapidly grow until a catastrophic failure occurs. Thus, the S–N curves of composites show a flatter curve when compared to the conventional materials. In terms of fatigue properties, conventional fiber‐reinforced composites (e.g., glass and carbon‐reinforced composites) were more extensively studied than bio‐based reinforced composites. Examining the fatigue properties of materials is significant for all engineering‐based applications. Because the fatigue failures can occur below the ultimate tensile strength of materials. However, the fatigue performance of the composites can be enhanced by improving the fiber‐matrix interfacial bonding resulting from surface treatment of fibers and incorporating nanofillers within the matrix, and so forth. Since the nanocomposites have a larger surface area and aspect ratio, they are preferred to use in many applications: aerospace, automotive, biotechnology, construction, and building, electronics, marine, and packing industries. Thus, this chapter starts with the unique advantages of bio‐nano composites. Then, the fatigue properties of bio‐nano composites, the significance of the S–N diagram, and the pattern of fatigue testing were discussed. In order to understand the fatigue behavior, several factors such as structure, fillers, fabrication techniques, and so forth were included. Challenges of fatigue strength of biocomposites were also summarized.
The term elastomer is a curtailment of two words, which are elastic and polymers. Accordingly, elastomers are polymer materials with elasticity. The significant challenges hindering the development of materials for naval applications, similar to other engineering sectors, include achieving a competitive light elastomeric structure. Marine structures are susceptible to various damage responses due to various loads throughout their service life. Being flexible, elastomer has a low modulus of elasticity, exhibits higher values of failure strain and yield strength. In these regards, elastomers are attractive materials for applications that require elasticity because they offer substantial advantages compared to traditional materials. However, the low fire resistance of these elastomeric materials jeopardizes their use in some critical applications. As a result, elastomeric blends and composites containing flame retardant (FR) additives are commonly used. On the other hand, elastomers possess (i) high strength-to-weight ratio, (ii) excellent impact properties, (iii) low infrared, magnetic, and radar signatures, (iv) excellent durability, and (v) high resilience to extreme loads. Hence, the scope of this study focuses on review and awareness regarding the feasibility of marine applications of elastomers/elastomeric composites, their current scientific and technological drawbacks, and future outlooks or prospects to support several applications in the marine industry.
A new hybrid fabrication technique was introduced to manufacture composite laminates made of glass fiber, carbon fiber, and acrylonitrile butadiene styrene (ABS) as the matrix. The fabrication process utilized two different techniques: fused deposition modeling and hot press molding. The composite laminates were produced using five layers of glass fibers to form glass fiber-reinforced composites (GF/ABS) and five layers of glass fiber and carbon fiber to form glass fiber, carbon fiber-reinforced hybrid composites (GF/CF/ABS), with three layers of glass fibers and two layers of carbon fibers. The fabricated composite laminates were subjected to wear testing at velocities of 2 m/s, 3 m/s, and 4 m/s and under loads of 5 N and 10 N. The results indicated that GF/ABS samples had the lowest wear loss at 5 N and a velocity of 4 m/s. Additionally, the GF/CF/ABS hybrid samples had the lowest coefficient of friction (COF) of 0.28 at 4 m/s. The GF/ABS samples also exhibited the lowest friction force of 1.7 at 5 N and a velocity of 4 m/s. The worn samples were analyzed using a scanning electron microscope to examine the fiber-to-matrix adhesion behavior. GF/ABS and GF/CF/ABS composites are widely used in various applications due to their high strength-to-weight ratio and resistance to wear. These materials could be used in automotive parts, sporting goods, and marine applications.
In this study, a hybrid manufacturing technique was proposed to fabricate composites of acrylonitrile butadiene styrene (ABS) with Bidirectional woven glass fiber mat (GF)/ABS and GF/Bidirectional woven carbon fiber mat (CF)/ABS. The composites were fabricated using fused deposition modeling 3D printing, followed by hot compression molding, and their flexural, impact, and dynamic mechanical behaviors were examined. Results indicated that composites with GF and ABS combinations had shown the highest maximum flexural strength (64.46 MPa) and impact strength (0.089 J/mm2). The hybrid composites showed intermediate performance between ABS and GF/ABS composites, with higher flexural strain before failure than ABS and GF/ABS. A comprehensive analysis utilizing scanning electron microscopy was carried out to evaluate the adhesion characteristics of the fiber‐matrix interface in impact‐tested samples. Dynamic mechanical analysis showed that GF/ABS composites had offered superior E′, E″, and tanδ than the hybrid configuration. The peak tan delta values obtained from ABS, GF/ABS, and GF/CF/ABS composites were utilized to determine their respective glass transition temperatures. The observed values for ABS, GF/ABS, and GF/CF/ABS composites were 109.65, 69.95, and 71.5°C, respectively. Some potential applications for the composites fabricated in this study could include the development of lightweight and strong components for aerospace or automotive industries.
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