Photovoltaic (PV) Levelized Cost of Energy (LCOE) estimates are widely utilized by decision makers to predict the long-term cost and benefits of solar PV installations, but fail to consider local climate, which impacts PV panel lifetime and performance. Specific types of solar PV panels are known to respond to climate factors differently. Mono-, poly-, and amorphous-silicon (Si) PV technologies are known to exhibit varying degradation rates and instantaneous power losses as a function of operating temperature, humidity, thermal cycling, and panel soiling. We formulate an extended LCOE calculation, which considers PV module performance and lifespan as a function of local climate. The LCOE is then calculated for crystalline and amorphous Si PV technologies across several climates. Finally, we assess the impact of various policy incentives on reducing the firm's cost of solar deployment when controlling for climate. This assessment is the first to quantify tradeoffs between technologies, geographies, and policies in a unified manner. Results suggest crystalline Si solar panels as the most promising candidate for commercial-scale PV systems due to their low degradation rates compared to amorphous technologies. Across technologies, we note the strong ability of investment subsidies in removing uncertainty and reducing the LCOE, compared to production incentives.
Slot die coating has been established as an economical approach for deposition of parallel narrow stripes, a constituent pattern feature in many printed device applications. However, the minimum feature size that can be achieved using this approach is constrained by wetting and liquid bridge phenomena at the deposition region. We hypothesize that pattern resolution and process control can be improved by co-depositing a support fluid to stabilize the pattern. Electrically conductive poly(3,4ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) is slot die-coated in parallel stripes on flexible poly(ethylene terephthalate) substrate, without wettability-enhancing dopants or substrate pretreatment. A miscible liquid phase, polyvinyl alcohol, is used as the support material. Feature size performance and conductivity of PEDOT:PSS stripe regions are evaluated across a range of process conditions. Narrow PEDOT:PSS stripes produced using our technique range from 400 to 850 μm and exhibit conductivity approaching 1.5 S cm −1 . This electrical performance falls within the upper range expected prior to standard conductivity-enhancing post-treatments. Significantly, dewetting effects normally present with undoped PEDOT:PSS on the plastic substrate are fully mitigated with our deposition technique. These results indicate high ease of processing and good feature size performance, with few inherent drawbacks to the functional properties of the patterned films.
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