Mulching has become an important practice in modern field production. Plastics are the most widespread mulching materials, and especially black polyethylene is used almost everywhere due to its low price and proved positive results in production. Together with its still growing popularity, there is increasing concern about the environmental effects of using such vast amounts of plastics in agriculture without solutions for sustainable and safe disposal of the material. There have been several attempts to try to find safe and environmentally friendly alternative materials to replace plastic mulches. The use of biodegradable films is increasing because they can be left safely in the field after harvesting, but they are not very durable and are much more expensive than plastics. Another alternative is paper. This article reviews the published research on paper mulches and discusses the opportunity that they offer for solving the problems of the immense use of plastics in agriculture and the associated environmental threat. Different mulching materials have been used for different agricultural and horticultural species in different climatic environments, and results vary according to the chosen approach, growing practices, conditions and species, so generalizations are hard to make. One advantage of paper mulches is that they do not create the disposal problems that plastic films always and partially degradable bio-films often do in long-term use. Paper mulches break down naturally after usage and incorporate into the soil. Laying paper mulches in large scale farming is a problem to be solved. The quality of the paper needs to be adapted or improved for mulching purposes, and its price needs to be more competitive with that of plastic mulches. The review shows that there is considerable potential for using paper mulches in agriculture and horticulture.

Synthetic structural materials of high mechanical performance are typically either of large weight (for example, steels, and alloys) or involve complex manufacturing processes and thus have high cost or cause adverse environmental impact (for example, polymer-based and biomimetic composites). In this perspective, low-cost, abundant and nature-based materials, such as wood, represent particular interest provided they fulfill the requirements for advanced engineering structures and applications, especially when manufactured totally additive-free. Here, we report on a novel all-wood material concept based on delignification, partial surface dissolution using ionic liquid (IL) followed by densification resulting in a high-performance material. A delignification process using sodium chlorite in acetate buffer solution was applied to controllably delignify the entire bulk wooden material while retaining the highly beneficial structural directionality of wood. In a subsequent step, obtained delignified porous wood template was infiltrated with an IL 1-ethyl-3methylimidazolium acetate, [EMIM]OAc and heat activated at 95 °C to partially dissolve the fiber surface. Afterward, treated wood was washed with water to remove IL and hot-pressed to gain a very compact cellulosic material with fused fibers while retaining unidirectional fiber orientation. The obtained cellulose materials were structurally, chemically, and mechanically characterized revealing superior tensile properties compared to native wood. Furthermore, suggested approach allows almost 8fold tensile strength improvement in the direction perpendicular to fiber orientation, which is otherwise very challenging to achieve.

Wood-based multifunctional materials with excellent mechanical performance are increasingly considered for sustainable advanced applications due to their unique hierarchical structure and inherent reinforcing cellulose phase orientation. Nonetheless, a wider multipurpose utilization of wood materials is so far hampered because of constraints arising from scalable functionalization, efficient processing, facile shaping as well asnatural heterogeneity and durability. This study introduces a multifunctional all-wood material fabrication method relying on delignification, ionic liquid (IL) treatment, and pressure-assisted consolidation of wood. Structure-retaining controlled delignification of wood was performed to enable direct access to the hierarchical cellulose assembly, while preserving the highly aligned and thus beneficial wood structural directionality. As a following step, the obtained biobased scaffold with an increased porosity was infiltrated with an IL and heat-activated to partially dissolve and soften the cellulose fiber surface. Samples washed with water to remove IL exhibited pronounced isotropic flexibility, which upon combined compression and lateral shear allowed the fabrication of various 3D shapes with adjustable fiber architecture. The obtained very compact and totally additive-free all-wood materials were extensively characterized, revealing superior mechanical performance, and gained multifunctionality compared to native wood.