No abstract

The increasing production of waste has led to one of the major environmental challenges of today: waste management. A solution to this problem is the composting of organic wastes. While the composting process transforms organic wastes into biologically stable compost, large amounts of highly contaminated leachates that present a direct risk to the environment are also produced. First off, this review discusses the origin and nature of contaminants found in composting leachates. In a general perspective, composting leachates are characterized by the presence of high concentrations of moderately biodegradable organic matter and nutrients and contain toxic pollutants such as heavy metals and plasticizers. Treatment technologies that have been studied are subsequently reported and discussed (treatment efficiencies and operating costs). This review highlights the lack of available solutions to efficiently remove all contaminants found in these leachates, which is a major concern considering the increasing number of composting facilities. While both, membrane bioreactors and reverse osmosis, show promising results with NH 4 , COD and TSS removals of [ 70, [ 85 and [ 99.9%, respectively, the resulting effluent remains hazardous for the environment. Further studies are required to assess the use of a combination of biological and advanced oxidation process for the production of a safely disposable effluent.

No abstract

In this study, the photolytic and photocatalytic removal of the herbicide paraquat is investigated under UV-C (254 nm). For photocatalytic experiments, SiC foams were used with P25-TiO nanoparticles deposited by dip-coating. The foams were characterized by scanning electron microscopy and paraquat's degradation under UV-C photolysis or photocatalysis, followed by UV-vis spectroscopy, total organic carbon analyzer, LC-MS and ion chromatography. After 3 h of reactions by photolysis and photocatalysis, 4% and 91% of TOC removal were observed. An analysis of degradation by-products showed a similar degradation pathway with pyridinium ions observed by LC/MS and carboxylic acids (succinate, acetate, oxalate and formate) detected by ion chromatography. In conclusion, these two different photo-degradation processes are able to remove paraquat and produce similar by-products. However, the kinetics of degradation is rather slow during photolysis and it is recommended to combine the UV-C lightning with a TiO photocatalyst to improve the mineralization rate.