Subnanometer copper tetramer−zirconia catalysts turn out to be highly efficient for CO 2 hydrogenation and its conversion to methane. The cluster size and substrate morphology are controlled to optimize the catalytic performance. The two types of zirconia supports investigated are prepared by atomic layer deposition (∼3 nm thick film) and supersonic cluster beam deposition (nanostructured film, ∼100 nm thick). The substrate plays a crucial role in determining the activity of the catalyst as well as its cyclability over repeated thermal ramps. A temperature-programmed reaction combined with in situ X-ray characterization reveals the correlation between the evolution in the oxidation state and catalytic activity. Ex situ photoelectron spectroscopy indicates Cu clusters with stronger interactions with the nanostructured film, which can be the cause for the higher activity of this catalyst. Density functional theory calculations based on the Cu 4 O 2 cluster supported on a ZrOx subunit reveal low activation barriers and provide mechanism for CO 2 hydrogenation and its conversion to methane. Altogether, the results show a new way to tune the catalytic activity of CO 2 hydrogenation catalysts through controlling the morphology of the support at the nanoscale.
The structure of a large dicationic silver hydride nanocluster was determined by X-ray crystallography. Pathways to the gas-phase liberation of hydrogen have been identified.
Here we describe a new conceptual approach for the design of a heterogeneous metal‐organic framework (MOF) catalyst based on UiO‐67 for the selective decarboxylation of formic acid, a reaction with important applications in hydrogen storage and in situ generation of H2. Models for the {CuH} reactive catalytic site at the organic linker are assessed. In the first model system, gas‐phase mass spectrometry experiments and DFT calculations on a fixed charge bathophen ligated copper hydride complex, [(phen*)Cu(H)]2−, were used to demonstrate that it acts as a catalyst for the selective decomposition of formic acid into H2 and CO2 via a two‐step catalytic cycle. In the first step liberation of H2 to form the carboxylate complex, [(phen*)Cu(O2CH)]2− occurs, which in the second step selectively decomposes via CO2 extrusion to regenerate the hydride complex. DFT calculations on four other model systems showed that changing the catalyst to neutral [(LCu(H)] complexes or embedding it within a MOF results in mechanisms which are essentially identical. Thus catalytic active sites located on the organic linker of a MOF appear to be close to a gas‐phase environment, thereby benefitting from the favorable characteristics of gas‐phase reactions and validating the use of gas‐phase models to design new MOF based catalysts.
A novel bisphosphine ligated Ag60 nanocluster, [{Cl@Ag12}@Ag48(dppm)12], has been discovered and characterized by X-ray crystallography. It consists of a central chloride located inside an icosahedral silver core layer, which is further encased by a second shell of 48 silver atoms/ions, which are capped with 12 bis(diphenylphosphino)methane (dppm) ligands. Due to lack of sufficient material the cluster could not be further characterized by other methods. DFT calculations were carried out on the cation [{Cl@Ag12}@Ag48(dppm)12]+ to determine if it corresponds to a superatom with a core count of n=58. The DFT optimized structure is in agreement with X-ray findings, but the low value of the HOMO-LUMO gap does not support superatom stability.
The theoretical concept of this paper serves to identify the key steps in the design of novel solar cells based on bio-nano hybrids (cyanidin-Agn) on a TiO2 surface for possible DSSC application.
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