Lithium-ion batteries (LIBs) are currently one of the most important electrochemical energy storage devices, powering electronic mobile devices and electric vehicles alike. However, there is a remarkable difference between their rate of production and rate of recycling. At the end of their lifecycle, only a limited number of LIBs undergo any recycling treatment, with the majority go to landfills or being hoarded in households. Further losses of LIB components occur because the the state-of-the-art LIB recycling processes are limited to components with high economic value, e.g., Co, Cu, Fe, and Al. With the increasing popularity of concepts such as “circular economy” (CE), new LIB recycling systems have been proposed that target a wider spectrum of compounds, thus reducing the environmental impact associated with LIB production. This review work presents a discussion of the current practices and some of the most promising emerging technologies for recycling LIBs. While other authoritative reviews have focused on the description of recycling processes, the aim of the present was is to offer an analysis of recycling technologies from a CE perspective. Consequently, the discussion is based on the ability of each technology to recover every component in LIBs. The gathered data depicted a direct relationship between process complexity and the variety and usability of the recovered fractions. Indeed, only processes employing a combination of mechanical processing, and hydro- and pyrometallurgical steps seemed able to obtain materials suitable for LIB (re)manufacture. On the other hand, processes relying on pyrometallurgical steps are robust, but only capable of recovering metallic components.
To reduce the loading of noble metals on fuel cell catalysts a synthesis method providing evenly distributed nanoparticles on the support surface is needed. Narrow size distribution palladium nanoparticles were prepared on a porous carbon support by atomic layer deposition (ALD), and their activity for ethanol and isopropanol oxidation was studied electrochemically in alkaline media. Palladium particles had smaller average particle sizes on the support material resulting in ∼50 mV lower onset potential and 2.5 times higher mass activity for alcohol oxidation compared with a commercial catalyst. The results indicate that the use of ALD allows the preparation of a noble metal nanoparticle catalyst, and this catalyst can provide similar mass activity with lower catalyst loading than current commercial fuel cell catalysts. This would significantly reduce the cost of the cell and provide a competitive advantage compared with other power sources.
The use of lithium-ion batteries (LIB) has grown significantly in recent years, making them a promising source of secondary raw materials due to their rich composition of valuable materials such as Co, Ni and Al. However, the high voltage and reactive components of LIBs pose safety hazards during crushing stages in recycling processes, and during storage and transportation. Electrochemical discharge by immersion of spent batteries in salt solutions has been generally accepted as a robust and straightforward discharging step to address these potential hazards. Nonetheless, there is no clear evidence in the literature to support the use of electrochemical discharge in real systems, neither are there clear indications of the real-world limitations of this practice. To that aim, this work presents a series of experiments systematically conducted to study the behavior of LIBs during electrochemical discharge in salt solutions. In the first part of this study, a LIB sample was discharged ex-situ using Pt wires connected to the battery poles and submerged into the electrolyte solution on the opposite end. The evolution of voltage in the battery was measured for solutions of NaCl, NaSO, FeSO, and ZnSO. The results indicate that, among the electrolytes used in the present study, NaCl solution is the most effective for LIBs discharge. The discharge of LIB using sulfate salts is however only possible with the aid of stirring, as deposition of solid precipitated on the electrodes hinder the electrochemical discharge. Furthermore, it was found that the addition of particulates of Fe or Zn as sacrificial metal further enhances the discharging rate, likely due to an increased contact area with the electrolyte solution. While these findings support the idea of using electrochemical discharge as a pre-treatment of LIBs, severe corrosion of the battery poles was observed upon direct immersion of batteries into electrolyte solutions. Prevention of such corrosion requires further research efforts, perhaps focused on a new design-for-recycling approach of LIBs.
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