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The control of chirality by optical molecular switches offers intriguing prospects in the design of new materials. For example, photochemically induced stilbene‐type cis‐trans isomerization of 1 (see Figure) results simultaneously in reversal of the helicity. The molecular design of switching units, the possibility of highly stereoselective optical molecular switching, and an approach to a gated response are described.
Mechanism of the transformation of a stiff polymer lyotropic nematic liquid crystal to the cholesteric state by dopant-mediated chiral information transfer Green, M.M.
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