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From a technological point of view, poly(lactic acid) (PLA) is one of the most important polymers produced from renewable sources, due to its versatility, relatively acceptable processability, and low cost. However, a significant limitation exists in its slow crystallization kinetics, which results in amorphous products having low mechanical properties and thermal resistance. For this reason, quantitative knowledge of the phenomenon of crystallization kinetics is fundamental. In this work, the crystallization kinetics in quiescent conditions of a commercial grade of PLA was analyzed in terms of nucleation and growth rates by direct morphological observations at different crystallization temperatures (Tc) and by calorimetric analysis in isothermal and non‐isothermal conditions. The optical analysis showed a spherulitic morphology with radial growth of the lamellae. The analysis of the growth rate evidenced the α/α'‐crystals polymorphism with a transition temperature of ~120°C. Based on experimental observation, the crystallization kinetics of the two crystalline phases were assessed.

Microinjection molding is one of the most efficient processes for wide‐scale production of thermoplastic polymer microparts. The injection molding process with a cold mold suffers from drawbacks, that is, the premature solidification, caused by the small thickness and large temperature difference between the surface of the mold and the incoming polymer. In this work, an original and versatile system to dynamically control the local temperature of the cavity surfaces in microinjection molding was developed. The system was used to investigate the effects of rapid variations of the temperature of a 200 μm thick cavity on the reachable flow length and study the morphology of microinjection molded parts of poly(lactic acid). For the rapid mold temperature control, electrical resistive thin components are located very near the surface of the impression to change the temperature by some tens of degrees per second. This study also demonstrates that the system is able to influence the final morphology of the part with a semicrystalline thermoplastic material. Changing the annealing time and temperature, the effects on the morphology of the part, in the mold and immediately after the injection, were investigated by microscopy analysis and X‐ray diffraction. POLYM. ENG. SCI., 58:586–591, 2018. © 2017 Society of Plastics Engineers

Poly(Lactic Acid), PLA represents a very interesting polymer for industrial applications because of its good processability, the possibility of being obtained from renewable sources, good physical properties, biocompatibility, and biodegradability. The major depolymerization mechanism and the step that controls the rate of PLA biodegradation in compost is represented by the hydrolysis. The characteristic of being degradable is not per se an advantage: the inclination to degrade in the presence of water represents a limit for specific industrial applications, especially for durable components that are designed for long-period utilization such as in the automotive, electronic, and agricultural sectors, as well as in medical applications. Being able to control the degradation rate would be a real advantage: a product should preserve its characteristics during processing and for a time comparable to its application but should be nevertheless fully biodegradable at longer times. Furthermore, a gradient of properties could allow producing samples in which some portions degrade at a faster rate and some others at a slower one. Different methods can be used to influence the degradation rate of PLA, some examples are blending, copolymerization and surface modification. However, these change the physical properties of the material. Any factor influencing the rate of hydrolysis can affect the biodegradation process. The objective of this work is verifying the possibility to modulate the rate of degradation in the same part, in time and at different rates. The method is represented by a technique that influences locally the morphology of the samples. Biphasic samples (half amorphous and the other half crystalline) were obtained by micro-injection molding and the degradation process was monitored by means of hydrolysis tests. The analysis confirmed the crystalline regions show a slightly better resistance to the hydrolysis compared to the amorphous.

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One of the most significant issues, when thin parts have to be obtained by injection molding (i.e. in micro-injection molding), is the determination of the conditions of pressure, mold temperature, and injection temperature to adopt to completely fill the cavity. Obviously, modern computational methods allow the simulation of the injection molding process for any material and any cavity geometry. However, this simulation requires a complete characterization of the material for what concerns the rheological and thermal parameters, and also a suitable criterion for solidification. These parameters are not always easily reachable. A simple test aimed at obtaining the required parameters is then highly advantageous. The so-called spiral flow test, consisting of measuring the length reached by a polymer in a long cavity under different molding conditions, is a method of this kind. In this work, with reference to an isotactic polypropylene, some spiral flow tests obtained with different mold temperatures and injection pressures are analyzed with a twofold goal: on one side, to obtain from a few simple tests the basic rheological parameters of the material; on the other side, to suggest a method for a quick prediction of the final flow length.

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