Phytoremediation is a technology based on the use of green plants to remove, relocate, deactivate, or destroy harmful environmental pollutants such as heavy metals, radionuclides, hydrocarbons, and pharmaceuticals. Under the general term of phytoremediation, several processes with distinctively different mechanisms of action are hidden. In this paper, the most popular modes of phytoremediation are described and discussed. A broad but concise review of available literature research with respect to the dominant process mechanism is provided. Moreover, methods of plant biomass utilization after harvesting, with particular regard to possibilities of “bio-ore” processing for metal recovery, or using energy crops as a valuable source for bio-energy production (bio-gas, bio-ethanol, bio-oil) are analyzed. Additionally, obstacles hindering the commercialization of phytoremediation are presented and discussed together with an indication of future research trends.
The purpose of this review is to provide insight and a comparison of the current status of district heating (DH) systems for selected Baltic Sea countries (Denmark, Germany, Finland, Latvia, Lithuania, Poland, and Sweden), especially from viewpoints of application and solutions of novel smart asset management (SAM) approaches. Furthermore, this paper considers European projects ongoing from 2016, involving participants from the Baltic Sea Region, concerning various aspects of DH systems. The review presents the energy sources with particular attention to renewable energy sources (RES), district heating generations, and the exploitation problems of DH systems. The essential point is a comparison of traditional maintenance systems versus SAM solutions for optimal design, operating conditions, and controlling of the DH networks. The main conclusions regarding DH systems in Baltic Sea countries are commitment towards a transition to 4th generation DH, raising the quality and efficiency of heat supply systems, and simultaneously minimizing the costs. The overall trends show that applied technologies aim to increase the share of renewable energy sources and reduce greenhouse gas emissions. Furthermore, examples presented in this review underline the importance of the implementation of a smart asset management concept to modern DH systems.
Due to the rising concentration of toxic nitrogen oxides (NOx) in the air, effective methods of NOx removal have been extensively studied recently. In the present study, the first developed WO3/S-doped g-C3N4 nanocomposite was synthesized using a facile method to remove NOx in air efficiently. The photocatalytic tests performed in a newly designed continuous-flow photoreactor with an LED array and online monitored NO2 and NO system allowed the investigation of photocatalyst layers at the pilot scale. The WO3/S-doped-g-C3N4 nanocomposite, as well as single components, were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller surface area analysis (BET), X-ray fluorescence spectroscopy (XRF), X-ray photoemission spectroscopy method (XPS), UV–vis diffuse reflectance spectroscopy (DR/UV–vis), and photoluminescence spectroscopy with charge carriers’ lifetime measurements. All materials exhibited high efficiency in photocatalytic NO2 conversion, and 100% was reached in less than 5 min of illumination under simulated solar light. The effect of process parameters in the experimental setup together with WO3/S-doped g-C3N4 photocatalysts was studied in detail. Finally, the stability of the composite was tested in five subsequent cycles of photocatalytic degradation. The WO3/S-doped g-C3N4 was stable in time and did not undergo deactivation due to the blocking of active sites on the photocatalyst’s surface.
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