The scientific paper analyzes the influence of the catalytically active surface on the intensity of heat and mass transfer in a chemically active boundary layer. Some features of the mechanism of heat and mass transfer under conditions of heterogeneous catalysis are indicated. Heat transfer analysis is performed in the laminar “frozen” boundary layer with zero and absolute catalytic surface activity. In order to improve the accuracy of the calculation of heat fluxes on the catalytically active surface, a modification of the Gullard ratio is carried out. Using the modified Gullard ratio obtained in this work, calculations of heat transfer on a catalytically active surface are carried out. It is shown that the levels of heat fluxes calculated using a modified ratio of up to 30% below the levels of heat fluxes obtained from the Gullard ratio under otherwise equal conditions.
The paper presents a method, tools and a newly developed algorithm for experimentally determining heat transfer coefficients in organic liquids and solutions. This work is made relevant by the problem of development of a new generation of aerospace technology. In this connection, improvements have been made to the pulse method of determining heat transfer coefficients that is based on the use of a micron-thick film sensor. The measurement setup was modified. A math model was constructed for the measuring sensor. Algorithms were developed for conducting the experiment and processing measurement results to determine heat transfer coefficients. Experimental uncertainties were analyzed. The paper provides results of experimental studies on certain organic liquids. The authors believe that the material presented in the paper will find application in research conducted at research institutions, engineering offices and universities, among researches, postgraduates and students.
Key words: thermal and physical characteristics, organic liquids and their solutions, film-type electrical resistor, thin-film temperature sensor, voltage pulse, resistance thermometer, irregular heat transfer regime.
This paper reviews the developed and tested algorithm of experimental determination of the catalycity coefficient of heat-proof thermal protection materials and determines the conditions which should be followed during the simulation process at high-temperature gas-dynamic testbeds within the experiment.
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