Exploration of proficient electrocatalyst from earth-abundant nonprecious metals in lieu of noble metal-based catalysts to obtain clean hydrogen energy through large-scale electrochemical water splitting is still an ongoing challenge. Herein, iron-doped nickel cobalt phosphide nanoplate arrays grown on a carbon cloth (NiCoFe x P/CC) are fabricated using a simple hydrothermal route, followed by phosphorization. The electrochemical analysis demonstrates that the NiCoFe x P/CC electrode possesses high electrocatalytic activity for water splitting in alkaline medium. Benefits from the synergistic effect between the metal centers, two-dimensional porous nanoplates, and unique threedimensional electrode configuration of NiCoFe x P/CC provide small overpotentials of 39 at 10 mA cm −2 and 275 mV at 50 mA cm −2 to drive the hydrogen evolution reaction and oxygen evolution reaction, respectively. Furthermore, the assembled two-electrode (NiCoFe x P/ CC∥NiCoFe x P/CC) alkaline water electrolyzer can achieve 10 mA cm −2 current density at 1.51 V. Remarkably, it can maintain stable electrolysis over 150 h. The excellent activity and stability of this catalyst is proved to be a economical substitute of commercial noble metal-based catalysts in technologies relevant to renewable energy.

We have developed a new highly fluorescent graphene oxide (GO)/poly(vinyl alcohol) (PVA) hybrid (GO-PVA) in an acidic medium (pH 4). Fourier transform infrared (FTIR) spectra indicate the formation of hydrogen bonds between the hydroxy group of PVA and the hydroxy groups of GO. The hybrid is highly fluorescent, because of passivation by hydrogen bonding, as evident from Raman spectra. The quantum yields of GO-PVA hybrids are higher than that of GO. The fluorescent microscopic images of the hybrids exhibit a fibrillar morphology, and all of them emit highly intense green light. Field-emission scanning electron microscopy (FESEM) micrographs also show a fibrillar morphology, which is produced due to the supramolecular organization of GO-PVA complex. The highly fluorescent GO-PVA1 hybrid has been used as a fascinating tool for selective sensing of Au(3+) ions in aqueous media with a detectable limit of ~275 ppb. The sensitivity of the Au(3+) ion (300 μM) in the presence of 600 μM concentrations of each ion (Cu(2+), Ag(+), Mg(2+), Ca(2+), Zn(2+), K(+), Pb(2+), Co(2+), Ni(2+), Pd(2+), Fe(2+), Fe(3+), and Cr(3+)), taken together, is unique, exhibiting a quenching efficiency of 76%. The quenching efficiency in the presence of a biologically analogous mixture (d-glucose, d-lysine, BSA, Na(+), K(+), Ca(2+), Mg(2+), Zn(2+)) (600 μM each) is 73%, which suggests that the GO-PVA1 hybrid is an efficient sensor of Au(3+) ions. The average lifetime of GO at pH 4 increases in the GO-PVA1 hybrid, indicating the formation of a more stable excited state but the increase in lifetime value after addition of Au(3+) salt solution to the hybrid solution indicates dynamic quenching. The selectivity of sensing of Au(3+) is attributed to its reduction potential being higher than that of other metal ions and XPS data of GO-PVA1 hybrid with 300 μM Au(3+) substantiate the reduction of Au(3+) to Au(0), because of the transfer of excitons from the hybrid facilitating the selective photoluminescence (PL) quenching.

Easily designed N-doped carbon/CC supported CoN–Ni3N nanograsses exhibit remarkable full electrochemical water splitting activity with excellent stability.

The electrochemical reduction of oxygen to water and the evolution of oxygen from water are two important electrode reactions extensively studied for the development of electrochemical energy conversion and storage technologies based on oxygen electrocatalysis. The development of an inexpensive, highly active, and durable nonprecious-metal-based oxygen electrocatalyst is indispensable for emerging energy technologies, including anion exchange membrane fuel cells, metal-air batteries (MABs), water electrolyzers, etc. The activity of an oxygen electrocatalyst largely decides the overall energy storage performance of these devices. Although the catalytic activities of Pt and Ru/Ir-based catalysts toward an oxygen reduction reaction (ORR) and an oxygen evolution reaction (OER) are known, the high cost and lack of durability limit their extensive use for practical applications. This review article highlights the oxygen electrocatalytic activity of the emerging non-Pt and non-Ru/Ir oxygen electrocatalysts including transition-metal-based random alloys, intermetallics, metal-coordinated nitrogen-doped carbon (M–N–C), and transition metal phosphides, nitrides, etc., for the development of an air-breathing electrode for aqueous primary and secondary zinc-air batteries (ZABs). Rational surface and chemical engineering of these electrocatalysts is required to achieve the desired oxygen electrocatalytic activity. The surface engineering increases the number of active sites, whereas the chemical engineering enhances the intrinsic activity of the catalyst. The encapsulation or integration of the active catalyst with undoped or heteroatom-doped carbon nanostructures affords an enhanced durability to the active catalyst. In many cases, the synergistic effect between the heteroatom-doped carbon matrix and the active catalyst plays an important role in controlling the catalytic activity. The ORR activity of these catalysts is evaluated in terms of onset potential, number of electrons transferred, limiting current density, and durability. The bifunctional oxygen electrocatalytic activity and ZAB performance, on the other hand, are measured in terms of potential gap between the ORR and OER, ΔE = E j10 OER – E 1/2 ORR, specific capacity, peak power density, open circuit voltage, voltaic efficiency, and charge–discharge cycling stability. The nonprecious metal electrocatalyst-based ZABs are very promising and they deliver high power density, specific capacity, and round-trip efficiency. The active site for oxygen electrocatalysis and challenges associated with carbon support is briefly addressed. Despite the considerable progress made with the emerging electrocatalysts in recent years, several issues are yet to be addressed to achieve the commercial potential of rechargeable ZAB for practical applications.

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Transition-metal-based heteronanoparticles are attracting extensive attention in electrode material design for supercapacitors owing to their large surface-to-volume ratios and inherent synergies of individual components; however, they still suffer from limited interior capacity and cycling stability due to simple geometric configurations, low electrochemical activity of the surface, and poor structural integrity. Developing an elaborate architecture that endows a larger surface area, high conductivity, and mechanically robust structure is a pressing need to tackle the existing challenges of electrode materials. This work presents a supercapacitor electrode consisting of honeycomb-like biphasic Ni 5 P 4 −Ni 2 P (Ni x P y ) nanosheets, which are interleaved by large quantities of nanoparticles. The optimized Ni x P y delivers an ultrahigh specific capacity of 1272 C g −1 at a current density of 2 A g −1 , high rate capability, and stability. An asymmetric supercapacitor employing as-synthesized Ni x P y as the positive electrode and activated carbon as the negative electrode exhibits significantly high power and energy densities (67.2 W h kg −1 at 0.75 kW kg −1 ; 20.4 W h kg −1 at 15 kW kg −1 ). These results demonstrate that the novel nanostructured Ni x P y can be potentially applied in highperformance supercapacitors.

Functionalized graphene-based drug delivery vehicles have conquered a significant position because functionalization improves its biocompatibility and stability in cell medium, leaving sufficient graphitic basal plane for drug loading through π-π stacking. In this study, poly(N-isopropylacrylamide) (PNIPAM) is covalently grafted from the surface of graphene oxide (GO) via a facile, eco-friendly and an easy procedure of free radical polymerization (FRP) using ammonium persulfate initiator. Various spectroscopic and microscopic studies confirm the successful grafting of PNIPAM from GO surface. PNIPAM-grafted GO (GPNM) exhibits enhanced thermal stability, improved dispersibility both in aqueous and cell medium, and better biocompatibility and cell viability compared to GO. Interestingly, GPNM displays an exciting fluorescence property in aqueous medium, which is a hike of intensity at 36 °C due to the lower critical solution temperature (LCST) of PNIPAM chains (32 °C). Moreover both hydrophilic (doxorubicin (DOX)) and hydrophobic (indomethacin (IMC)) drugs loaded on the surface of GPNM hybrid exhibits its efficacy as an efficient carrier for both types of drugs. Cellular uptakes of free DOX and DOX-loaded GPNM (GPNM-DOX) are evidenced both from optical and fluorescence imaging of live cells, and the efficiency of drug is significantly improved in the loaded system. The release of DOX from GPNM-DOX was achieved at pH 4, relevant to the environment of cancer cells. The pH-triggered release of hydrophobic drug was also studied using UV-vis spectroscopy via alginate encapsulation, showing a great enhancement at pH = 7.4. The IMC is also found to be released by human serum albumin using dialysis technique. The GPNM nanomaterial shows the property of simultaneous loading of DOX and IMC as well as pH-triggered simultaneous release of both of the drugs.