ZnO-TiO 2 nanocomposites were synthesized by an innovative chemical vapor deposition (CVD) strategy, based on the initial growth of ZnO nanoplatelets (host) and the subsequent dispersion of TiO 2 nanoparticles (guest). Ti(O i Pr) 2 (dpm) 2 and Zn(hfa) 2
Zinc oxide nanoplatelets are successfully grown on Si(100) by CVD starting from a second-generation Zn II precursor, Zn(hfa) 2 ÁTMEDA (Hhfa = 1,1, 1,5,5, TMEDA= N,N,N′,. The synthesis is performed in a nitrogen + wet oxygen atmosphere under optimized conditions, at temperatures between 250 and 500°C. Field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and glancing incidence X-ray diffraction (GIXRD) analyses indicate a direct correlation between morphology and microstructure. The formation of ZnO nanoplatelets, whose characteristics depend on the deposition temperature, is proposed to result from the synergistic combination of a vapor/solid (VS) mechanism and a preferential direction-conducting growth. The chemical composition is analyzed by means of X-ray photoelectron and energy dispersive X-ray spectroscopies (XPS, EDXS). Finally, the photocatalytic performances of ZnO nanoplatelets in the decomposition of the azo-dye Orange II are investigated and compared to those of uniform ZnO coatings synthesized in the absence of water vapor. The obtained results show a higher activity in the case of nanoplatelets due to their peculiar morphology.
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